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Bromido[(1,2,5,6-?)-cyclo-octa-1,5-diene]methyl-platinum(II).

ABSTRACT: In the title complex, [PtBr(CH(3))(C(8)H(12))], the Pt(II) ion is in a distorted square-planar environment defined by the Br and methyl C atoms and the mid-points of the two ?-coordinated double bonds of cyclo-octa-1,5-diene. As a result of the different trans influences of the Br atom and the methyl group, the Pt-C bonds trans to the methyl group [2.262?(11) and 2.261?(10)?Å] are longer than those trans to the Br atom [2.118?(8) and 2.138?(9)?Å].

SUBMITTER: Ha K 

PROVIDER: S-EPMC2980049 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Bromido[(1,2,5,6-η)-cyclo-octa-1,5-diene]methyl-platinum(II).

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title complex, [PtBr(CH(3))(C(8)H(12))], the Pt(II) ion is in a distorted square-planar environment defined by the Br and methyl C atoms and the mid-points of the two π-coordinated double bonds of cyclo-octa-1,5-diene. As a result of the different trans influences of the Br atom and the methyl group, the Pt-C bonds trans to the methyl group [2.262 (11) and 2.261 (10) Å] are longer than those trans to the Br atom [2.118 (8) and 2.138 (9) Å]. ...[more]

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