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Rational synthesis and characterization of highly water stable MOF@GO composite for efficient removal of mercury (Hg²⁺) from water.

ABSTRACT: The present study is aimed at adsorptive removal of Mercury (Hg²⁺) using highly functionalized nanomaterials based on Graphene Oxide Zeolitic Imidazolate Framework composite (ZIF-67@GO). Solvothermal methodology was used to synthesize ZIF-67@GO composite. Synthesized compounds were confirmed by FTIR, SEM, PXRD and EDX analysis. The as-prepared ZIF-67@GO was tested as efficient adsorbent for effective removal of Mercury (Hg²⁺) from aquatic environment. The atomic adsorption spectrophotometer was used to monitor the process of adsorption of Hg⁺² on ZIF-67@GO. From the adsorption data, the maximum removal efficiency achieved was 91.1% using 10 mg amount of composite for 50 mL using 20 ppm Mercury (Hg²⁺) solution. Different parameters like pH, contact time, concentration, adsorption kinetics and isotherm were also examined to explore adsorption process. Adsorption data fitted well for Freundlich Model having R² value of 0.9925 than Langmuir Isotherm with R² value of 0.9238. Kinetics were rapid and excellently described via 2nd order model with R² = 0.99946 than 1st order model with R² value of 0.8836. Freundlich and pseudo 2nd order models validated that multilayer chemisorption occurs during adsorption process due to the presence of highly functionalized sites on ZIF-67@GO composite. The synthesized composite material has shown excellent reusability. Thus, water stable ZIF-67@GO composites can efficiently be used for Mercury (Hg²⁺) confiscation from water.

SUBMITTER: Fallatah AM

PROVIDER: S-EPMC9579000 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature

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Rational synthesis and characterization of highly water stable MOF@GO composite for efficient removal of mercury (Hg2+) from water.

Fallatah Ahmed M AM Shah Habib Ur Rehman HUR Ahmad Khalil K Ashfaq Muhammad M Rauf Abdul A Muneer Muhammad M Ibrahim Mohamed M MM El-Bahy Zeinhom M ZM Shahzad Amir A Babras Afshain A

Heliyon 20221005 10

The present study is aimed at adsorptive removal of Mercury (Hg2+) using highly functionalized nanomaterials based on Graphene Oxide Zeolitic Imidazolate Framework composite (ZIF-67@GO). Solvothermal methodology was used to synthesize ZIF-67@GO composite. Synthesized compounds were confirmed by FTIR, SEM, PXRD and EDX analysis. The as-prepared ZIF-67@GO was tested as efficient adsorbent for effective removal of Mercury (Hg2+) from aquatic environment. The atomic adsorption ...[more]

PMID: 36276714

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Project description:AimsTo screen heavy metal-tolerant strains from heavy metal-contaminated soil in mining areas and determine the tolerance of the strains to different heavy metals and their removal rates through experiments.MethodsMercury-resistant strain LBA119 was isolated from mercury-contaminated soil samples in Luanchuan County, Henan Province, China. The strain was identified by Gram staining, physiological and biochemical tests, and 16S rDNA sequences. The LBA119 strain showed good resistance and removal rates to heavy metals such as Pb2+, Hg2+, Mn2+, Zn2+, and Cd2+ using tolerance tests under optimal growth conditions. The mercury-resistant strain LBA119 was applied to mercury-contaminated soil to determine the ability of the strain to remove mercury from the soil compared to mercury-contaminated soil without bacterial biomass.ResultsMercury-resistant strain LBA119 is a Gram-positive bacterium that appears as a short rod under scanning electron microscopy, with a single bacterium measuring approximately 0.8 × 1.3 μm. The strain was identified as a Bacillus by Gram staining, physiological and biochemical tests, and 16S rDNA sequence analysis. The strain was highly resistant to mercury, with a minimum inhibitory concentration (MIC) of 32 mg/L for mercury. Under a 10 mg/L mercury environment, the optimal inoculation amount, pH, temperature, and salt concentration of the LBA119 strain were 2%, 7, 30 °C, and 20 g/L, respectively. In the 10 mg/L Hg2+ LB medium, the total removal rate, volatilization rate, and adsorption rate at 36 h were 97.32%, 89.08%, and 8.24%, respectively. According to tolerance tests, the strain showed good resistance to Pb2+, Mn2+, Zn2+, Cd2+, and other heavy metals. When the initial mercury concentration was 50 mg/L and 100 mg/L, compared with the mercury-contaminated soil that contained an LB medium without bacterial biomass, LBA119 inoculation increased 15.54-37.67% after 30 days of culture.ConclusionThis strain shows high bioremediation potential for mercury-contaminated soil.

Project description:A novel chelating adsorbent, based on the functionalization of activated carbon (AC) derived from water hyacinth (WH) with melamine thiourea (MT) to form melamine thiourea-modified activated carbon (MT-MAC), is used for the effective removal of Hg2+, Pb2+, and Cd2+ from aqueous solution. Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) theory confirm the successful functionalization of AC with the melamine thiourea chelating ligand through the amidation reaction between the carboxyl groups of oxidized activated carbon (OAC) and the amino groups of melamine thiourea (MT) in the presence of dicyclohexylcarbodiimide (DCC) as a coupling agent. The prepared MT-MAC exhibited extensive potential for the adsorption of the toxic metal ions Hg2+, Pb2+, and Cd2+ from wastewater. The MT-MAC showed high capacities for the adsorption of Hg2+ (292.6 mg·g-1), Pb2+ (237.4 mg·g-1), and Cd2+ (97.9 mg·g-1) from aqueous solution. Additionally, 100% removal efficiency of Hg2+ at pH 5.5 was observed at very low initial concentrations (25-1000 ppb).The experimental sorption data could be fitted well with the Langmuir isotherm model, suggesting a monolayer adsorption behavior. The kinetic data of the chemisorption mechanism realized by the melamine thiourea groups grafted onto the activated carbon surface have a perfect match with the pseudo-second-order (PSO) kinetic model. In a mixed solution of metal ions containing 50 ppm of each ion, MT-MAC showed a removal of 97.0% Hg2+, 68% Pb2+, 45.0% Cd2+, 17.0% Cu2+, 7.0% Ni2+, and 5.0% Zn2+. Consequently, MT-MAC has exceptional selectivity for Hg2+ ions from the mixed metal ion solutions. The MT-MAC adsorbent showed high stability even after three adsorption-desorption cycles. According to the results obtained, the use of the MT-MAC adsorbent for the adsorption of Pb2+, Hg2+, and Cd2+ metal ions from polluted water is promising.

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Rational synthesis and characterization of highly water stable MOF@GO composite for efficient removal of mercury (Hg²⁺) from water.

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Rational synthesis and characterization of highly water stable MOF@GO composite for efficient removal of mercury (Hg<sup>2+</sup>) from water.

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