Sustainable Synthesis of MOF-5@GO Nanocomposites for Efficient Removal of Rhodamine B from Water.
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ABSTRACT:
SUBMITTER: Kumar G
PROVIDER: S-EPMC8047673 | biostudies-literature |
REPOSITORIES: biostudies-literature
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Project description:A magnetic Fe3O4/GO composite with potential for rapid solid-liquid separation through a magnetic field was synthesized using GO (graphene oxide) and Fe3O4 (ferriferous oxide). Characterization of Fe3O4/GO used scanning electron microscope (SEM), X-ray diffractometer (XRD), Fourier transform infrared spectrometer (FT-IR), and Vibrating Sample Magnetometer (VSM). A number of factors such as pH and coexisting ions on adsorbent dose were tested in a series of batch experiments. The results showed that GO and Fe3O4 are strongly integrated. For pH values in the range of 3.0~9.0, the removal efficiency of Sb(III) using the synthesized Fe3O4/GO remained high (95%). The adsorption showed good fit to a pseudo-second-order and Langmiur model, with the maximum adsorption capacity of 9.59 mg/g maintained across pH 3.0-9.0. Thermodynamic parameters revealed that the adsorption process was spontaneous and endothermic. Analysis by X-ray photoelectron spectroscopy (XPS) showed that the adsorption process is accompanied by a redox reaction.
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Project description:In this study, by hybridization of zinc-based metal-organic framework-5 (MOF-5) and melamine-terephthaldehyde-based intergrade two-dimensional ?-conjugated covalent organic framework (COF), a novel MOF-5/COF (M5C) hybrid material was prepared and characterized by Fourier transform infrared, field emission scanning electron microscopy, X-ray diffraction, and thermogravimetric analysis. MOF-5 has a well-defined cubic structure, and the proposed COF has an orderly and spherical nanosize shape. The prepared MOF-5/COF was applied as an effective adsorbent for rapid and high-efficient simultaneous removal of auramine O (AO) and rhodamine B (RB) cationic dyes via electrostatic, H-bonding, Lewis acid-base interactions, and ?-? stacking from aqueous solution. The effect of experimental parameters such as pH, M5C mass, contact time, and AO and RB dyes concentration was investigated for removal efficiency and optimized. The M5C adsorbent showed an adsorption capacity of 17.95 and 16.18 mg/g for AO and RB dyes, respectively, at pH 9.5. The adsorption study of AO and RB dyes by M5C comprises both isotherm and kinetic studies. The equilibrium adsorption data followed by Langmuir isotherm and the adsorption kinetic process were found to be a pseudo-second-order model. The robustness adsorption efficiency of MOF/COF hybrids can be attributed to the formation of amide bonds between COF and MOFs, which improve the stability of the adsorbent.
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