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Determination of heavy metals contamination in thyme products by inductively coupled plasma mass spectrometry.

ABSTRACT: Thyme herbs constitute a major part of the Mediterranean diet and are gaining worldwide popularity. However, their chemical contamination with toxic metals may put consumers at a health risk. The objective of this study was to assess the incidence of Arsenic (As), Cadmium (Cd), Lead (Pb) and Mercury (Hg) in thyme-containing products. Composite samples were collected twice at six-month interval. Samples were digested by microwave digestion oven and analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). 11%, 22%, and 86% of samples had unacceptable levels of As, Hg and Pb respectively according to the international standards set by Codex Alimentarius and all the samples had acceptable limits of Cd. This study highlighted the importance of monitoring and enforcing regulatory actions related to the contamination of the food chain with heavy metals.

SUBMITTER: Akoury E

PROVIDER: S-EPMC9742941 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Determination of heavy metals contamination in thyme products by inductively coupled plasma mass spectrometry.

Akoury Elias E Baroud Caline C El Kantar Sally S Hassan Hussein H Karam Layal L

Toxicology reports 20221027

Thyme herbs constitute a major part of the Mediterranean diet and are gaining worldwide popularity. However, their chemical contamination with toxic metals may put consumers at a health risk. The objective of this study was to assess the incidence of Arsenic (As), Cadmium (Cd), Lead (Pb) and Mercury (Hg) in thyme-containing products. Composite samples were collected twice at six-month interval. Samples were digested by microwave digestion oven and analyzed by Inductively Coupled Plasma Mass Spec ...[more]

PMID: 36518480

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Project description:Rapid, sensitive and simultaneous determination of trace multi-elements in various plant food samples such as grain, oilseed, vegetable and tea is always a challenge thus far. In this work, a rapid determination method for Se, Cd, As and Pb in food samples by inductively coupled plasma mass spectrometry (ICP-MS) using slurry sampling electrothermal vaporization (SS-ETV) was developed. To improve the analytical sensitivity and precision as well as eliminate the memory effect, a gas turbulator line and signal delay device (SDD) were for the first time designed for the graphite furnace (GF) ETV coupled with ICP-MS. The signal acquisition parameters of ICP-MS, ashing and vaporization conditions, and the flow rates of carrier gas and gas turbulator were investigated for Se, Cd, As and Pb in food samples. Under the optimized conditions, the limits of determination (LODs) for Se, Cd, As and Pb were 0.5 ng g-1, 0.3 ng g-1, 0.3 ng g-1 and 0.6 ng g-1, respectively; the limits of quantification (LOQs) for Se, Cd, As and Pb were 1.7 ng g-1, 1.0 ng g-1, 1.0 ng g-1 and 1.9 ng g-1, respectively; linearity (R2) in the range of 1 to 4,000 ng g-1 was >0.999 using the standard addition method. This method was used to analyze 5 CRMs including rice, tea and soybeans, and the concentrations detected by this method were within the range of the certified values. The recoveries of Se, Cd, As and Pb in plant food matrices including grain, oilseed, celery, spinach, carrot and tea samples were 86-118% compared to the microwave digestion ICP-MS method; and the relative standard deviations (RSDs) were 1.2-8.9% for real food sample analysis, proving a good precision and accuracy for the simultaneous determination of multi-elements. The analysis time was less than 3 min, slurry preparation time < 5 min without sample digestion process. The proposed direct slurry sampling ICP-MS method is thus suitable for rapid and sensitive determination of Se, Cd, As and Pb in food samples with advantages such as simplicity, green and safety, as well as with a promising application potential in detecting more elements to protect food safety and human health.

Dataset Information

Determination of heavy metals contamination in thyme products by inductively coupled plasma mass spectrometry.

Publications

Determination of heavy metals contamination in thyme products by inductively coupled plasma mass spectrometry.

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