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Stacked nanocarbon photosensitizer for efficient blue light excited Eu(III) emission.

ABSTRACT: Photosensitizer design to allow effective use of low-energy light is important for developing photofunctional materials. Herein, we describe a rational photosensitizer design for effective use of low-energy light. The developed photosensitizer is a stacked nanocarbon based on a rigid polyaromatic framework, which allows efficient energy transfer from the low-energy T₁ level to the energy acceptor. We prepared an Eu(III) complex consisting of a luminescent center (Eu(III)) and stacked-coronene photosensitizer. The brightness of photosensitized Eu(III) excited using low-energy light (450 nm) is more than five times higher than the maximum brightness of previously reported Eu(III) complexes.

SUBMITTER: Kitagawa Y

PROVIDER: S-EPMC9812264 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Stacked nanocarbon photosensitizer for efficient blue light excited Eu(III) emission.

Kitagawa Yuichi Y Suzue Fumiya F Nakanishi Takayuki T Fushimi Koji K Seki Tomohiro T Ito Hajime H Hasegawa Yasuchika Y

Communications chemistry 20200103 1

Photosensitizer design to allow effective use of low-energy light is important for developing photofunctional materials. Herein, we describe a rational photosensitizer design for effective use of low-energy light. The developed photosensitizer is a stacked nanocarbon based on a rigid polyaromatic framework, which allows efficient energy transfer from the low-energy T1 level to the energy acceptor. We prepared an Eu(III) complex consisting of a luminescent center (Eu(III)) and stacked- ...[more]

PMID: 36703320

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