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Crystal structure of 2-(morpholino)ethyl-ammonium picrate monohydrate.

ABSTRACT: The title compound, C₆H₁₅N₂O⁺·C₆H₂N₃O₇ ^-·H₂O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C₆H₁₅N₂O)⁺, one anion (C₆H₂N₃O₇)^- and a water mol-ecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C-H⋯O, O-H⋯O, O-H⋯N and N-H⋯O hydrogen-bonding inter-actions and π-π stacking. The inter-molecular inter-actions of the synthesized compound were qu-anti-fied by Hirshfeld surface analysis.

SUBMITTER: Chidambaranathan B

PROVIDER: S-EPMC9815139 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of 2-(morpholino)ethyl-ammonium picrate monohydrate.

Chidambaranathan Balasubramanian B Sivaraj Settu S Selvakumar Shanmugam S

Acta crystallographica. Section E, Crystallographic communications 20230101 Pt 1

The title compound, C6H15N2O+·C6H2N3O7 -·H2O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C6H15N2O)+, one anion (C6H2N3O7)- and a water mol-ecule in the asymmetric unit. The morpholi ...[more]

PMID: 36628364

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