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4-Nitro-phenyl-hydrazinium picrate monohydrate.

ABSTRACT: In the crystal structure of the title compound, C6H8N3O2 (+)·C6H2N3O7 (-)·H2O, N-H?O and O-H?O hydrogen bonds link the components into a two-dimensional network parallel to (010). In addition, there are pairs of weak inversion-related C-H?O hydrogen bonds within the two-dimensional network. The three nitro groups are twisted by 1.6?(3), 7.8?(3) and 12.1?(3)° from the ring plane in the anion, while in the cation, the nitro group makes a dihedral angle of 4.6?(2)° with the ring.

SUBMITTER: Cai HL

PROVIDER: S-EPMC3914065 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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4-Nitro-phenyl-hydrazinium picrate monohydrate.

Cai Hong-Lan HL Liu Bing B Qiao Qing-An QA

Acta crystallographica. Section E, Structure reports online 20131207 Pt 1

In the crystal structure of the title compound, C6H8N3O2 (+)·C6H2N3O7 (-)·H2O, N-H⋯O and O-H⋯O hydrogen bonds link the components into a two-dimensional network parallel to (010). In addition, there are pairs of weak inversion-related C-H⋯O hydrogen bonds within the two-dimensional network. The three nitro groups are twisted by 1.6 (3), 7.8 (3) and 12.1 (3)° from the ring plane in the anion, while in the cation, the nitro group makes a dihedral angle of 4.6 (2)° with the ring. ...[more]

PMID: 24526966

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