Tailored Synthesis of Catalytically Active Cerium Oxide for N, N-Dimethylformamide Oxidation.

ABSTRACT: Cerium oxide nanopowder (CeO_x) was prepared using the sol-gel method for the catalytic oxidation of N, N-dimethylformamide (DMF). The phase, specific surface area, morphology, ionic states, and redox properties of the obtained nanocatalyst were systematically characterized using XRD, BET, TEM, EDS, XPS, H₂-TPR, and O₂-TPO techniques. The results showed that the catalyst had a good crystal structure and spherelike morphology with the aggregation of uniform small grain size. The catalyst showed the presence of more adsorbed oxygen on the catalyst surface. XPS and H₂-TPR have confirmed the reduction of Ce⁴⁺ species to Ce³⁺ species. O₂-TPR proved the reoxidability of CeO_x, playing a key role during DMF oxidation. The catalyst had a reaction rate of 1.44 mol g^-1_cat s^-1 and apparent activation energy of 33.30 ± 3 kJ mol^-1. The catalytic performance showed ~82 ± 2% DMF oxidation at 400 °C. This work's overall results demonstrated that reducing Ce⁴⁺ to Ce³⁺ and increasing the amount of adsorbed oxygen provided more suitable active sites for DMF oxidation. Additionally, the catalyst was thermally stable (~86%) after 100 h time-on-stream DMF conversion, which could be a potential catalyst for industrial applications.

SUBMITTER: Fonzeu Monguen CK 

PROVIDER: S-EPMC9867243 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature