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An Inorganic Fluorescent Chemosensor: Rational Design and Selective Mg2+ Detection.


ABSTRACT: A Zn2+ based complex, 3, displays greatly increased fluorescence emission in the presence of Mg2+. Fluorescent and computational studies suggest that 3 selectively interacts with Mg2+ due to optimal cavity size formation between two uncoordinated pyrazole side arms. This work thus represents a new approach to the development of fluorescent chemosensors.

SUBMITTER: Gerard T 

PROVIDER: S-EPMC9893466 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature

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An Inorganic Fluorescent Chemosensor: Rational Design and Selective Mg<sup>2+</sup> Detection.

Gerard Theodore T   Wei Yang Y   Weerawardhana Erwin E   Lugosan Adriana A   Zeller Matthias M   Dickie Diane A DA   Li Pengfei P   Lee Wei-Tsung WT  

ACS omega 20230119 4


A Zn<sup>2+</sup> based complex, <b>3</b>, displays greatly increased fluorescence emission in the presence of Mg<sup>2+</sup>. Fluorescent and computational studies suggest that <b>3</b> selectively interacts with Mg<sup>2+</sup> due to optimal cavity size formation between two uncoordinated pyrazole side arms. This work thus represents a new approach to the development of fluorescent chemosensors. ...[more]

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