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Efficient Solar Light Photocatalyst Made of Ag₃PO₄ Coated TiO₂-SiO₂ Microspheres.

ABSTRACT: Solar light active photocatalyst was prepared as silver phosphate (Ag₃PO₄) coating on titania-silica (TiO₂-SiO₂) microspheres. Titania-silica microsphere was obtained by spray drying TiO₂-SiO₂ colloidal solutions, whereas Ag₃PO₄ was applied by wet impregnation. XRD on the granules and SEM analysis show that the silver phosphate particles cover the surface of the titania-silica microspheres, and UV-visible diffuse reflectance analysis highlights that Ag₃PO₄/TiO₂-SiO₂ composites can absorb the entire visible light spectrum. BET measurements show higher specific surface area of the composite samples compared to bare Ag₃PO₄. Photocatalytic activity was evaluated by dye degradation tests under solar light irradiation. The prepared catalysts follow a pseudo-first-order rate law for dye degradation tests under solar light irradiation. The composite catalysts with an Ag₃PO₄/TiO₂-SiO₂ ratio of 1:1.6 wt% show better catalytic activity towards both rhodamine B and methylene blue degradation and compared with the results with uncoated TiO₂-SiO₂ microspheres and the benchmark commercial TiO₂ (Evonik-P25) as a reference. The composite photocatalyst showed exceptional efficiency compared to its pristine counterparts and reference material. This is explained as having a higher surface area with optimum light absorption capacity.

SUBMITTER: Pal S

PROVIDER: S-EPMC9921011 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Efficient Solar Light Photocatalyst Made of Ag3PO4 Coated TiO2-SiO2 Microspheres.

Pal Sudipto S Padmanabhan Sanosh Kunjalukkal SK Kaitheri Amruth A Epifani Mauro M Licciulli Antonio A

Nanomaterials (Basel, Switzerland) 20230201 3

Solar light active photocatalyst was prepared as silver phosphate (Ag3PO4) coating on titania-silica (TiO2-SiO2) microspheres. Titania-silica microsphere was obtained by spray drying TiO2-SiO2 colloidal solutions, whereas Ag3PO4 was applied by wet impregnation. XRD on the granules and SEM analysis show that the silver phosphate particles cover the surface of the titania-silica microspheres, and UV-visible dif ...[more]

PMID: 36770549

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Project description:Bacterial and organic pollutants are major problems with potential adverse impacts on human health and the environment. A promising strategy to alleviate these impacts consists in designing innovative photocatalysts with a wider spectrum of application. In this paper, we report the improved photocatalytic and antibacterial activities of chemically precipitated Ag3PO4 microcrystals by the incorporation of W at doping levels 0.5, 1, and 2 mol %. The presence of W directly influences the crystallization of Ag3PO4, affecting the morphology, particle size, and surface area of the microcrystals. Also, the characterization via experimental and theoretical approaches evidenced a high density of disordered [AgO4], [PO4], and [WO4] structural clusters due to the substitution of P5+ by W6+ into the Ag3PO4 lattice. This leads to new defect-related energy states, which decreases the band gap energy of the materials (from 2.27 to 2.04 eV) and delays the recombination of e'-h• pairs, leading to an enhanced degradation process. As a result of such behaviors, W-doped Ag3PO4 (Ag3PO4:W) is a better visible-light photocatalyst than Ag3PO4, demonstrated here by the photodegradation of potential environmental pollutants. The degradation of rhodamine B dye was 100% in 4 min for Ag3PO4:W 1%, and for Ag3PO4, the obtained result was 90% of degradation in 15 min of reaction. Ag3PO4:W 1% allowed the total degradation of cephalexin antibiotic in only 4 min, whereas pure Ag3PO4 took 20 min to achieve the same result. For the degradation of imidacloprid insecticide, Ag3PO4:W 1% allowed 90% of degradation, whereas Ag3PO4 allowed 40%, both in 20 min of reaction. Moreover, the presence of W-dopant results in a 16-fold improvement of bactericidal performance against methicillin-resistant Staphylococcus aureus. The outstanding results using the Ag3PO4:W material demonstrated its potential multifunctionality for the control of organic pollutants and bacteria in environmental applications.

Dataset Information

Efficient Solar Light Photocatalyst Made of Ag₃PO₄ Coated TiO₂-SiO₂ Microspheres.

Publications

Efficient Solar Light Photocatalyst Made of Ag<sub>3</sub>PO<sub>4</sub> Coated TiO<sub>2</sub>-SiO<sub>2</sub> Microspheres.

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