Unknown

Dataset Information

0

Stereochemistry of 1-(4'-hydroxyphenyl)ethanol produced by hydroxylation of 4-ethylphenol by p-cresol methylhydroxylase.


ABSTRACT: Enzymic hydroxylation of 4-ethylphenol by (a) Pseudomonas putida and (b) highly purified p-cresol methylhydroxylase gave optically active 1-(4'-hydroxyphenyl)-ethanol. The products were transformed into the phenolic methyl ethers and shown to contain 69.5% and 65.6%, respectively, of the (S)-(-)-isomer. The stereochemistry of the reaction is discussed in terms of three distinct steps occurring at the active site of the enzyme.

SUBMITTER: McIntire W 

PROVIDER: S-EPMC1144472 | biostudies-other | 1984 Dec

REPOSITORIES: biostudies-other

Similar Datasets

| S-EPMC1144990 | biostudies-other
| S-EPMC1144991 | biostudies-other
| S-EPMC1186072 | biostudies-other
| S-EPMC3804855 | biostudies-literature
| S-EPMC196977 | biostudies-other
| S-EPMC1177839 | biostudies-other
| S-EPMC5895980 | biostudies-literature
2021-08-04 | GSE181333 | GEO
| S-EPMC1177837 | biostudies-other
2021-04-13 | GSE156116 | GEO