Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Rapid synthesis of small silver nanocubes by mediating polyol reduction with a trace amount of sodium sulfide or sodium hydrosulfide.

ABSTRACT: This paper describes the fastest route to monodispersed silver nanocubes. By adding a trace amount of sodium sulfide (Na(2)S) or sodium hydrosulfide (NaHS) to the conventional polyol synthesis, the reaction time was significantly shortened from 16-26 hours to 3-8 minutes. By merely adjusting the reaction time, monodispersed silver nanocubes of 25-45 nm in edge length were rapidly and routinely produced on relatively large scales. These small nanocubes are of great interest for biomedical applications by way of generating gold nanocages with plasmon resonance peaks tunable to the near-infrared region through a galvanic replacement reaction.

SUBMITTER: Siekkinen AR

PROVIDER: S-EPMC2390781 | biostudies-other | 2006 Dec

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Rapid synthesis of small silver nanocubes by mediating polyol reduction with a trace amount of sodium sulfide or sodium hydrosulfide.

Siekkinen Andrew R AR McLellan Joseph M JM Chen Jingyi J Xia Younan Y

Chemical physics letters 20061201 4-6

This paper describes the fastest route to monodispersed silver nanocubes. By adding a trace amount of sodium sulfide (Na(2)S) or sodium hydrosulfide (NaHS) to the conventional polyol synthesis, the reaction time was significantly shortened from 16-26 hours to 3-8 minutes. By merely adjusting the reaction time, monodispersed silver nanocubes of 25-45 nm in edge length were rapidly and routinely produced on relatively large scales. These small nanocubes are of great interest for biomedical applica ...[more]

PMID: 18496589

Similar Datasets

Selective and rapid extraction of trace amount of gold from complex liquids with silver(I)-organic frameworks.

Project description:The design of adsorbents for rapid, selective extraction of ultra-trace amounts of gold from complex liquids is desirable from both an environmental and economical point of view. However, the development of such materials remains challenging. Herein, we report the fabrication of two vinylene-linked two-dimensional silver(I)-organic frameworks prepared via Knoevenagel condensation. This material enables selective sensing of gold with a low limit of detection of 60 ppb, as well as selective uptake of ultra-trace gold from complex aqueous mixtures including distilled water with 15 competing metal ions, leaching solution of electronic waste (e-waste), wastewater, and seawater. The present adsorbent delivers a gold adsorption capacity of 954 mg g-1, excellent selectivity and reusability, and can rapidly and selectively extract ultra-trace gold from seawater down to ~20 ppb (94% removal in 10 minutes). In addition, the purity of recovered gold from e-waste reaches 23.8 Karat (99.17% pure).

| S-EPMC9755257 | biostudies-literature

Synthesis of Ag nanocubes 18-32 nm in edge length: the effects of polyol on reduction kinetics, size control, and reproducibility.

Project description:This article describes a robust method for the facile synthesis of small Ag nanocubes with edge lengths controlled in the range of 18-32 nm. The success of this new method relies on the substitution of ethylene glycol (EG)--the solvent most commonly used in a polyol synthesis--with diethylene glycol (DEG). Owing to the increase in hydrocarbon chain length, DEG possesses a higher viscosity and a lower reducing power relative to EG. As a result, we were able to achieve a nucleation burst in the early stage to generate a large number of seeds and a relatively slow growth rate thereafter; both factors were critical to the formation of Ag nanocubes with small sizes and in high purity (>95%). The edge length of the Ag nanocubes could be easily tailored in the range of 18-32 nm by quenching the reaction at different time points. For the first time, we were able to produce uniform sub-20 nm Ag nanocubes in a hydrophilic medium and on a scale of ?20 mg per batch. It is also worth pointing out that the present protocol was remarkably robust, showing good reproducibility between different batches and even for DEGs obtained from different vendors. Our results suggest that the high sensitivity of synthesis outcomes to the trace amounts of impurities in a polyol, a major issue for reproducibility and scale up synthesis, did not exist in the present system.

| S-EPMC3576731 | biostudies-literature

Silver Nanocubes as Electrochemical Labels for Bioassays.

Project description:Here, we report on the use of 40 ± 4 nm silver nanocubes (AgNCs) as electrochemical labels in bioassays. The model metalloimmunoassay combines galvanic exchange (GE) and anodic stripping voltammetry (ASV). The results show that a lower limit of detection is achieved by simply changing the shape of the Ag label yielding improved GE with AgNCs when compared to GE with spherical silver nanoparticles (sAgNPs). Specifically, during GE between electrogenerated Au3+ and the Ag labels, a thin shell of Au forms on the surface of the NP. This shell is more porous when GE proceeds on AgNCs compared to sAgNPs, and therefore, more exchange occurs when using AgNCs. ASV results show that the Ag collection efficiency (AgCE%) is increased by up to ∼57% when using AgNCs. When the electrochemical system is fully optimized, the limit of detection is 0.1 pM AgNCs, which is an order of magnitude lower than that of sAgNP labels.

| S-EPMC8005456 | biostudies-literature

Feasibility of Rapid Diagnostic Technology for SARS-CoV-2 Virus Using a Trace Amount of Saliva.

Project description:Containment of SARS-CoV-2 has become an urgent global issue. To overcome the problems of conventional quantitative polymerase chain reaction (qPCR) tests, we verified the usefulness of a mobile qPCR device that utilizes mouthwash to obtain a saliva sample with the aim of developing a rapid diagnostic method for SARS-CoV-2. First, we examined whether anyone could easily operate this device. Then, we examined whether RNA in the mouthwash could be detected in a short time. In addition, we investigated whether it was possible to diagnose SARS-CoV-2 infection using mouthwash obtained from COVID-19 patients undergoing hospitalization. The results revealed that all subjects were able to complete the operation properly without error. In addition, RNase P was detected in the mouthwash without pretreatment. The average detection time was 18 min, which is significantly shorter than conventional qPCR devices. Furthermore, this device detected SARS-CoV-2 in the mouthwash of a COVID-19 patient undergoing hospitalization. The above findings verified the efficacy of this diagnostic method, which had a low risk of infection, was technically simple, and provided stable results. Therefore, this method is useful for the rapid detection of SARS-CoV-2.

| S-EPMC8625231 | biostudies-literature

Refractive index and formaldehyde sensing with silver nanocubes.

Project description:We report the synthesis of Ag nanocubes by using a sodium sulfide assisted solvothermal method. Small edge-length nanocubes (32 and 44 nm) were obtained at 145 and 155 °C reaction temperature in the synthesis process. The refractive index sensitivity of synthesized nanocubes was investigated with an aqueous solution of glucose. The refractive index sensitivity of 161 nm per RIU was found in the colloidal dispersion of nanocubes. On the LSPR chip made by immobilization of nanocubes on the (3-aminopropyl)trimethoxysilane modified glass coverslip, the obtained sensitivity was 116 nm per RIU. Detection of formaldehyde in water and milk samples was also performed with nanocubes of edge-length of 44 nm. Formaldehyde detection was performed by utilizing the interaction of the aryl amine of 4-aminothiophenol immobilized on the nanocubes and electrophilic carbon atom of the formaldehyde. In water and in diluted milk, the formaldehyde sensitivity of 0.62 and 0.29 nm μM-1 was obtained, respectively.

| S-EPMC8695105 | biostudies-literature

Isolating and probing the hot spot formed between two silver nanocubes.

Project description:Out of the frying pan: Hot spots can greatly increase the sensitivity of surface-enhanced Raman scattering, but they remain poorly understood. A new strategy based on plasma etching (see picture) can be used to isolate and exclusively probe the SERS-active molecules adsorbed in the hot-spot region between two silver nanocubes.

| S-EPMC2978425 | biostudies-literature

Advances in Low-Density Flexible Polyurethane Foams by Optimized Incorporation of High Amount of Recycled Polyol.

Project description:An industrially manufactured recycled polyol, obtained by acidolysis process, was for the first time proved to be a possible replacement of the reference fossil-based polyol in a low-density formulation suitable for industrial production of flexible polyurethane foams. The influence of increasing recycled polyol amounts on the properties of the polyurethane foam has been studied, also performing foam emission tests to evaluate the environmental impact. Using 10 pbw recycled polyol in the standard formulation, significant differences of the physical properties were not observed, but increase of the recycled polyol amount to 30 pbw led to a dramatic decrease of the foam air flow and a very tight foam. To overcome this drawback, N,N'-bis[3-(dimethylamino)propyl]urea was selected as tertiary amine catalyst, enabling the preservation of foam properties even at high recycled polyol level (30 pbw). Foam emission data demonstrated that this optimized foam formulation also led to an important reduction of volatile organic compounds. The results open the way for further optimization studies in low-density flexible polyurethane foam formulations, to increase the reutilization of the polyurethane waste and reduce the amount of petroleum-based raw materials.

| S-EPMC8198888 | biostudies-literature

From Silver Plates to Spherical Nanoparticles: Snapshots of Microwave-Assisted Polyol Synthesis.

Project description:The fabrication of silver nanoparticles (Ag NPs) with different sizes by microwave (MW)-assisted synthesis is presented. The fast heating of the MW technique, combined with the possibility to thermally quench the reactions, enabled us to capture snapshots of nucleation and growth processes difficult to accomplish in other techniques. The Ag NPs were synthesized using poly(vinylpyrrolidone) (PVP) through a polyol approach. The effects of the reaction time, the reaction temperatures, and the silver precursor concentration were investigated. The influence of agitation, the PVP concentration, and the initial conditions of the silver precursor was also studied. It is found that at very short reaction times and at low temperatures, polyhedral plates are formed with sizes ca. 300 nm and large polydispersity. However, by increasing the time or the temperature, a size and shape refinement is observed resulting in 10 nm spherical NPs with low polydispersity. Mechanistic insights are provided based on the observations extracted from transmission electron microscopy (TEM) and ultraviolet-visible spectroscopy (UV-vis). A formation mechanism starting from kinetically favored silver polyhedral plates to thermodynamically favored spherical nanoparticles is proposed. Understanding these effects allowed us to control the particle size and the tuning of Ag NPs on-demand. Moreover, the reproducibility and scalability of the process and the long-term stability of the NPs in aqueous solutions are demonstrated. Finally, we provide a recommendation regarding the use of fresh PVP as a capping and stabilizing agent.

| S-EPMC7097931 | biostudies-literature

Trace Amount of NiP2 Cooperative CoMoP Nanosheets Inducing Efficient Hydrogen Evolution.

Project description:As a very attractive clean energy, hydrogen has a high energy density and great potential to achieve zero pollution emission. Therefore, the preparation of hydrogen evolution electrocatalysts with excellent performance is an urgent task to ameliorate the global energy shortage and environmental pollution. Here, a trace amount of NiP2 coupled with CoMoP nanosheets (NCMP) was synthesized by the one-step hydrothermal method and low-temperature phosphidation. Studies have found that although the dosage of NiP2 is very low, its appearance has been efficient to improve the hydrogen evolution reaction (HER) performance of CoMoP, which may be induced by the synergistic effect of the two different components NiP2 and CoMoP. To find the superior catalyst, the effect of Ni content on the catalyst performance is also studied, and it is found that when the dosage of Ni is 0.02 mM, NCMP-2 (2 means 0.02 mM) displays the most outstanding overpotential (10 mA cm-2) of 46 mV.

| S-EPMC8655887 | biostudies-literature

Mapping Localized Surface Plasmons within Silver Nanocubes Using Cathodoluminescence Hyperspectral Imaging.

Project description:Localized surface plasmons within silver nanocubes less than 50 nm in size were investigated using high-resolution cathodoluminescence hyperspectral imaging. Multivariate statistical analysis of the multidimensional luminescence data set allows both the identification of distinct spectral features in the emission and the mapping of their spatial distribution. These results show a 490-nm peak emitted from the cube faces, with shorter-wavelength luminescence coming from the vertices and edges; this provides direct experimental confirmation of theoretical predictions.

| S-EPMC3660952 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data