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Cu(I)-catalyzed asymmetric diamination of conjugated dienes.

ABSTRACT: A Cu(I)-catalyzed asymmetric diamination for a variety of conjugated dienes and a triene with encouraging ee's has been effectively achieved using (R)-DTBM-SEGPHOS as a chiral ligand and di- tert-butyldiaziridinone as the nitrogen source.

SUBMITTER: Du H 

PROVIDER: S-EPMC2659555 | biostudies-other | 2008 Oct

REPOSITORIES: biostudies-other

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Cu(I)-catalyzed asymmetric diamination of conjugated dienes.

Du Haifeng H   Zhao Baoguo B   Yuan Weicheng W   Shi Yian Y  

Organic letters 20080903 19

A Cu(I)-catalyzed asymmetric diamination for a variety of conjugated dienes and a triene with encouraging ee's has been effectively achieved using (R)-DTBM-SEGPHOS as a chiral ligand and di- tert-butyldiaziridinone as the nitrogen source. ...[more]

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