Browse
Submit Data
Databases
API
Help

Dataset Information

21 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Optical properties of anisotropic core-shell pyramidal particles.

ABSTRACT: This paper describes an approach to fabricate anisotropic core-shell particles by assembling dielectric beads within fabricated noble metal pyramidal structures. Particles with gold (Au) shells and different dielectric cores were generated, and their optical properties were characterized by single particle spectroscopy. Because of their unique geometry, these particles exhibit multiple plasmon resonances from visible to near-IR wavelengths.

SUBMITTER: Sweeney CM

PROVIDER: S-EPMC2670351 | biostudies-other | 2009 Apr

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Optical properties of anisotropic core-shell pyramidal particles.

Sweeney Christina M CM Hasan Warefta W Nehl Colleen L CL Odom Teri W TW

The journal of physical chemistry. A 20090401 16

This paper describes an approach to fabricate anisotropic core-shell particles by assembling dielectric beads within fabricated noble metal pyramidal structures. Particles with gold (Au) shells and different dielectric cores were generated, and their optical properties were characterized by single particle spectroscopy. Because of their unique geometry, these particles exhibit multiple plasmon resonances from visible to near-IR wavelengths. ...[more]

PMID: 19290590

Similar Datasets

Optoelectronic Properties in Near-Infrared Colloidal Heterostructured Pyramidal "Giant" Core/Shell Quantum Dots.

Project description:Colloidal heterostructured quantum dots (QDs) are promising candidates for next-generation optoelectronic devices. In particular, "giant" core/shell QDs (g-QDs) can be engineered to exhibit outstanding optical properties and high chemical/photostability for the fabrication of high-performance optoelectronic devices. Here, the synthesis of heterostructured CuInSe x S2-x (CISeS)/CdSeS/CdS g-QDs with pyramidal shape by using a facile two-step method is reported. The CdSeS/CdS shell is demonstrated to have a pure zinc blend phase other than typical wurtzite phase. The as-obtained heterostructured g-QDs exhibit near-infrared photoluminescence (PL) emission (?830 nm) and very long PL lifetime (in the microsecond range). The pyramidal g-QDs exhibit a quasi-type II band structure with spatial separation of electron-hole wave function, suggesting an efficient exciton extraction and transport, which is consistent with theoretical calculations. These heterostructured g-QDs are used as light harvesters to fabricate a photoelectrochemical cell, exhibiting a saturated photocurrent density as high as ?5.5 mA cm-2 and good stability under 1 sun illumination (AM 1.5 G, 100 mW cm-2). These results are an important step toward using heterostructured pyramidal g-QDs for prospective applications in solar technologies.

| S-EPMC6097093 | biostudies-literature

Magnetic and optical properties of multifunctional core-shell radioluminescence nanoparticles.

Project description:When X-rays irradiate radioluminescence nanoparticles, they generate visible and near infrared light that can penetrate through centimeters of tissue. X-ray luminescence tomography (XLT) maps the location of these radioluminescent contrast agents at high resolution by scanning a narrow X-ray beam through the tissue sample and collecting the luminescence at every position. Adding magnetic functionality to these radioluminescent particles would enable them to be guided, oriented, and heated using external magnetic fields, while their location and spectrum could be imaged with XLT and complementary magnetic resonance imaging. In this work, multifunctional monodispersed magnetic radioluminescent nanoparticles were developed as potential drug delivery carriers and radioluminescence imaging agents. The particles consisted of a spindle-shaped magnetic ?-Fe2O3 core and a radioluminescent europium-doped gadolinium oxide shell. Particles with solid iron oxide cores displayed saturation magnetizations consistent with their ~13% core volume, however, the iron oxide quenched their luminescence. In order to increase the luminescence, we partially etched the iron oxide core in oxalic acid while preserving the radioluminescent shell. The core size was controlled by the etching time which in turn affected the particles' luminescence and magnetic properties. Particles with intermediate core sizes displayed both strong magnetophoresis and luminescence properties. They also served as MRI contrast agents with relaxivities of up to 58 mM-1s-1 (r2) and 120 mM-1s-1 (r2*). These particles offer promising multimodal MRI/fluorescence/X-ray luminescence contrast agents. Our core-shell synthesis technique offers a flexible method to control particle size, shape, and composition for a wide range of biological applications of magnetic/luminescent nanoparticles.

| S-EPMC3918467 | biostudies-literature

ZnSe/ZnS Core/Shell Quantum Dots with Superior Optical Properties through Thermodynamic Shell Growth.

Project description:Epitaxial growth of a protective semiconductor shell on a colloidal quantum dot (QD) core is the key strategy for achieving high fluorescence quantum efficiency and essential stability for optoelectronic applications and biotagging with emissive QDs. Herein we investigate the effect of shell growth rate on the structure and optical properties in blue-emitting ZnSe/ZnS QDs with narrow emission line width. Tuning the precursor reactivity modifies the growth mode of ZnS shells on ZnSe cores transforming from kinetic (fast) to thermodynamic (slow) growth regimes. In the thermodynamic growth regime, enhanced fluorescence quantum yields and reduced on-off blinking are achieved. This high performance is ascribed to the effective avoidance of traps at the interface between the core and the shell, which are detrimental to the emission properties. Our study points to a general strategy to obtain high-quality core/shell QDs with enhanced optical properties through controlled reactivity yielding shell growth in the thermodynamic limit.

| S-EPMC7467768 | biostudies-literature

Non-resonant Mie scattering: emergent optical properties of core-shell polymer nanowires.

Project description:We provide the in-depth characterization of light-polymer nanowire interactions in the context of an effective Mie scattering regime associated with low refractive index materials. Properties of this regime sharply contrast with these of resonant Mie scattering, and involve the formation of strictly forward-scattered and coupling-free optical fields in the vicinity of core-shell polymer nanowires. Scattering from these optical fields is shown to be non-resonant in nature and independent from incident polarization. In order to demonstrate the potential utility of this scattering regime in one-dimensional (1D) polymeric nanostructures, we fabricate polycarbonate (PC) - polyvinylidene difluoride (PVDF) core-shell nanowires using a novel iterative thermal drawing process that yields uniform and indefinitely long core-shell nanostructures. These nanowires are successfully engineered for novel nanophotonics applications, including size-dependent structural coloration, efficient light capture on thin-film solar cells, optical nano-sensors with ultrahigh sensitivity and a mask-free photolithography method suitable for the straightforward production of 1D nanopatterns.

| S-EPMC3980223 | biostudies-literature

MXene Core-Shell Nanosheets: Facile Synthesis, Optical Properties, and Versatile Photonics Applications.

Project description:In recent years, the transition metal carbonitrides(MXenes) have been widely applied to photoelectric field, and better performance of these applications was achieved via MXene complex structures. In our work, we proposed a MXene core-shell nanosheet composed of a Ti2C (MXene) phase and gold nanoparticles, and applied it to mode-locked and single-frequency fiber laser applications. The optoelectronic results suggested that the performances of these two applications were both improved when MXene core-shell nanosheets were applied. As a result, we obtained a mode-locking operation with 670 fs pulses, and the threshold pump power reached to as low as 20 mW. Besides, a single-frequency laser with the narrowest linewidth of ~1 kHz is also demonstrated experimentally. Our research work proved that MXene core-shell nanosheets could be used as saturable absorbers (SAs) to promote versatile photonic applications.

| S-EPMC8398170 | biostudies-literature

The Effect of Magnetic Field on Catalytic Properties in Core-Shell Type Particles.

Project description:Magnetic field effects can provide a handle on steering chemical reactions and manipulating yields. The presence of a magnetic field can influence the energy levels of the active species by interacting with their spin states. Here we demonstrate the effect of a magnetic field on the electrocatalytic processes taking place on platinum-based nanoparticles in fuel cell conditions. We have identified a shift in the potentials representing hydrogen adsorption and desorption, present in all measurements recorded in the presence of a magnetic field. We argue that the changes in electrochemical behavior are a result of the interactions between the magnetic field and the unpaired spin states of hydrogen.

| S-EPMC7082754 | biostudies-literature

Au@Ag core-shell nanocubes with finely tuned and well-controlled sizes, shell thicknesses, and optical properties.

Project description:This paper describes a facile method for generating Au@Ag core-shell nanocubes with edge lengths controllable in the range of 13.4-50 nm. The synthesis involved the use of single-crystal, spherical Au nanocrystals of 11 nm in size as the seeds in an aqueous system, with ascorbic acid serving as the reductant and cetyltrimethylammonium chloride (CTAC) as the capping agent. The thickness of the Ag shells could be finely tuned from 1.2 to 20 nm by varying the ratio of AgNO(3) precursor to Au seeds. We also investigated the growth mechanism by examining the effects of seeds (capped by CTAC or cetyltrimethylammonium bromide(CTAB)) and capping agent (CTAC vs CTAB) on both size and shape of the resultant core-shell nanocrystals. Our results clearly indicate that CTAC worked much better than CTAB as a capping agent in both the syntheses of Au seeds and Au@Ag core-shell nanocubes. We further studied the localized surface plasmon resonance properties of the Au@Ag nanocubes as a function of the Ag shell thickness. By comparing with the extinction spectra obtained from theoretical calculations, we derived a critical value of ca. 3 nm for the shell thickness at which the plasmon excitation of the Au cores would be completely screened by the Ag shells. Moreover, these Au@Ag core-shell nanocubes could be converted into Au-based hollow nanostructures containing the original Au seeds in the interiors through a galvanic replacement reaction.

| S-EPMC2997519 | biostudies-literature

Optical Properties of Nested Pyramidal Nanoshells.

Project description:This paper describes the fabrication and characterization of nested Au pyramidal nanoshells. These particles exhibited two plasmon resonances at visible and near-infrared wavelengths that could be manipulated depending on the size of the gap between inner and outer pyramidal shells. We found that larger gaps (30 nm) exhibited much larger Raman scattering responses compared to smaller gaps (5 nm) in the nested pyramidal shells. The SERS-activity of these anisotropic particles can be optimized by adjusting the distances between the inner and outer Au shells.

| S-EPMC2812899 | biostudies-literature

From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties.

Project description:The optical properties of metallic nanoparticles are highly sensitive to interparticle distance, giving rise to dramatic but frequently irreversible color changes. By electrochemical modification of individual nanoparticles and nanoparticle pairs, we induced equally dramatic, yet reversible, changes in their optical properties. We achieved plasmon tuning by oxidation-reduction chemistry of Ag-AgCl shells on the surfaces of both individual and strongly coupled Au nanoparticle pairs, resulting in extreme but reversible changes in scattering line shape. We demonstrated reversible formation of the charge transfer plasmon mode by switching between capacitive and conductive electronic coupling mechanisms. Dynamic single-particle spectroelectrochemistry also gave an insight into the reaction kinetics and evolution of the charge transfer plasmon mode in an electrochemically tunable structure. Our study represents a highly useful approach to the precise tuning of the morphology of narrow interparticle gaps and will be of value for controlling and activating a range of properties such as extreme plasmon modulation, nanoscopic plasmon switching, and subnanometer tunable gap applications.

| S-EPMC4672758 | biostudies-literature

Tailored Synthesis of Core-Shell Mesoporous Silica Particles-Optimization of Dye Sorption Properties.

Project description:Monodisperse spherical silica particles, with solid cores and mesoporous shells (SCMS), were synthesized at various temperatures using a one-pot method utilizing a cationic surfactant template. The temperature of the synthesis was found to significantly affect the diameters of both the cores (ca. 170-800 nm) and shells (ca. 11-80 nm) of the particles, which can be tailored for specific applications that require a high specific surface area of the nanocarriers (mesoporous shells) and simultaneously their mechanical robustness for, e.g., facile isolation from suspensions (dense cores). The applied method enabled the formation of the relatively thick mesoporous shells at conditions below room temperature. Radially ordered pores with narrow distributions of their sizes in 3-4 nm range were found in the shells. The adsorption ability of the SCMS particles was studied using rhodamine 6G as a model dye. Decolorization of the dye solution in the presence of the SCMS particles was correlated with their structure and specific surface area and reached its maximum for the particles synthesized at 15 °C. The presented strategy may be applied for the fine-tuning of the structure of SCMS particles and the enhancement of their adsorption capabilities.

| S-EPMC5923560 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data