Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

The solid solution Na(0.39)(NH(4))(1.61)SO(4)·Te(OH)(6).

ABSTRACT: The title compound, sodium ammonium sulfate-telluric acid (1/1), Na(0.39)(NH(4))(1.61)SO(4)·Te(OH)(6), is isostructural with other solid solutions in the series M(1-x)(NH(4))(x)SO(4)·Te(OH)(6), where ammonium is partially replaced with an alkali metal (M = K, Rb or Cs). The structure is composed of planes of Te(OH)(6) octa-hedra alternating with planes of SO(4) tetra-hedra. The Na(+)/NH(4) (+) cations are statistically distributed over the same position and are located between the planes. The structure is stabilized by O-H?O and N-H?O hydrogen bonds between the telluric acid adducts and the O atoms of sulfate groups, and between the ammonium cations and O atoms, respectively. Both Te atoms lie on centres of symmetry.

SUBMITTER: Ktari L

PROVIDER: S-EPMC2960854 | biostudies-other | 2008

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

The solid solution Na(0.39)(NH(4))(1.61)SO(4)·Te(OH)(6).

Ktari Lilia L Abdelhedi Mohamed M Dammak Mohamed M Cousson Alain A Kolsi Abdelwaheb A

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3

The title compound, sodium ammonium sulfate-telluric acid (1/1), Na(0.39)(NH(4))(1.61)SO(4)·Te(OH)(6), is isostructural with other solid solutions in the series M(1-x)(NH(4))(x)SO(4)·Te(OH)(6), where ammonium is partially replaced with an alkali metal (M = K, Rb or Cs). The structure is composed of planes of Te(OH)(6) octa-hedra alternating with planes of SO(4) tetra-hedra. The Na(+)/NH(4) (+) cations are statistically distributed over the same position and are located between the planes. The st ...[more]

PMID: 21201836

Similar Datasets

Na(5)(NH(4))Mn(3)[B(9)P(6)O(33)(OH)(3)]·1.5H(2)O.

Project description:The overall hexa-gonal framework of the title compound, penta-sodium ammonium trimanganese(II) borophosphate sesquihydrate, consists of tube-like borophosphate anions, (?) (1){[B(3)P(2)O(11)(OH)](4-)}, made up of corner-sharing PO(4) and BO(4) tetra-hedra and BO(2)(OH) triangles, forming ten-membered ring windows. The tubes are inter-connected via distorted MnO(6) octa-hedra, establishing a three-dimensional open-framework structure with two different types of ring-channels (12- and six-membered) that run along [001]. The 12-membered ring channels are occupied by NH(4) (+) ions and water mol-ecules. The ten-membered ring windows in the walls of the tubes are occupied by Na(+) ions. The remaining Na(+) ions and the water mol-ecules, one of which is half-occupied, reside within the six-membered ring channels. The structural setup is consolidated by an O-H?O hydrogen bond between the OH group and an opposite O atom of the framework. Donor-acceptor distances ranging from 2.80 to 3.35?Å between the ammonium N atom, water O atoms and framework O atoms indicate further hydrogen-bonding inter-actions.

| S-EPMC2959984 | biostudies-literature

Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH3NH2]1-x [NH3OH] x Zn(HCOO)3.

Project description:We report how mechanical and dynamical properties in formate-based perovskites can be manipulated by the preparation of an A-site solid-solution. In the series [NH3NH2]1-x [NH3OH] x Zn(HCOO)3 with xmax = 0.48, the substitution of [NH3NH2]+ by [NH3OH]+ is accompanied by a series of complex changes in crystal chemistry which are analysed using PXRD, SCXRD, 1H solid state NMR, DSC and nanoindentation. NMR shows increased motion of [NH3NH2]+ in [NH3NH2]0.52[NH3OH]0.48Zn(HCOO)3, which results in a shift of the ferroelectric-to-paraelectric phase transition temperature from Tc = 352 K (x = 0) to Tc = 324 K (x = 0.48). Additionally, the loss of hydrogen bonds directly influences the mechanical response of the framework; the elastic moduli and hardnesses decrease by around 25% from E110 = 24.6 GPa and H110 = 1.25 GPa for x = 0, to E110 = 19.0 GPa and H110 = 0.97 GPa for x = 0.48. Our results give an in-depth insight into the crystal chemistry of ABX3 formate perovskites and highlight the important role of hydrogen bonding and dynamics.

| S-EPMC6020122 | biostudies-literature

An experimental and theoretical NMR study of NH-benzimidazoles in solution and in the solid state: proton transfer and tautomerism.

Project description:This paper reports the (1)H, (13)C and (15)N NMR experimental study of five benzimidazoles in solution and in the solid state ((13)C and (15)N CPMAS NMR) as well as the theoretically calculated (GIAO/DFT) chemical shifts. We have assigned unambiguously the "tautomeric positions" (C3a/C7a, C4/C7 and C5/C6) of NH-benzimidazoles that, in some solvents and in the solid state, appear different (blocked tautomerism). In the case of 1H-benzimidazole itself we have measured the prototropic rate in HMPA-d 18.

| S-EPMC4142846 | biostudies-literature

The solid solution K3.84Ni0.78Fe3.19(PO4)5.

Project description:The title compound, tetra-potassium tetra-[nickel(II)/iron(III)] penta-kis-(orthophosphate), K3.84Ni0.78Fe3.19(PO4)5, has been obtained from a flux. The structure is isotypic with that of K4MgFe3(PO4)5. The three-dimensional framework is built up from (Ni/Fe)O5 trigonal bipyramids with a mixed Fe:Ni occupancy of 0.799?(8):0.196?(10) and isolated PO4 tetra-hedra, one of which is on a general position and one of which has -4.. site symmetry. Two K(+) cations are statistically occupied and are distributed over two positions in hexa-gonally shaped channels that run parallel to [001]. One K(+) cation [occupancy 0.73?(3)] is surrounded by nine O atoms, while the other K(+) cation [occupancy 0.23?(3)] is surrounded by eight O atoms.

| S-EPMC4120600 | biostudies-literature

α-SrZn5-Type solid solution, BaZn2.6Cu2.4.

Project description:Single crystals of the title compound barium zinc copper, BaCu2.6Zn2.4, were obtained from a sample prepared by heating metal chips of Ba, Cu, and Zn in an Ar atmosphere up to 973 K, followed by slow cooling. Single-crystal X-ray structure analysis revealed that BaCu2.6Zn2.4 crystallizes in an ortho-rhom-bic cell [a = 12.9858 (3), b = 5.2162 (1), and c = 6.6804 (2) Å] with an α-SrZn5-type structure (space group Pnma). The three-dimensional framework consists of Cu and Zn atoms, with Ba atoms in the tunnels extending in the b-axis direction. Although the Ba atom is larger than the Sr atom, the cell volume of BaCu2.6Zn2.4 [452.507 (19) Å3] is smaller than that of α-SrZn5 [466.08 Å3]. This decrease in volume can be attributed to the partial substitution of Cu atoms by Zn atoms in the framework because the Cu-Zn and Cu-Cu bonds are shorter than the Zn-Zn bond. The increase in Ba-Zn inter-atomic distances from the Sr-Zn distances is cancelled out by the partial replacement of Zn with Cu atoms, which leads to shorter average Ba-Zn/Cu distances.

| S-EPMC6775754 | biostudies-literature

Solution-Deposited Solid-State Electrochromic Windows.

Project description:Commercially available electrochromic (EC) windows are based on solid-state devices in which WO3 and NiOx films commonly serve as the EC and counter electrode layers, respectively. These metal oxide layers are typically physically deposited under vacuum, a time- and capital-intensive process when using rigid substrates. Herein we report a facile solution deposition method for producing amorphous WO3 and NiOx layers that prove to be effective materials for a solid-state EC device. The full device containing these solution-processed layers demonstrates performance metrics that meet or exceed the benchmark set by devices containing physically deposited layers of the same compositions. The superior EC performance measured for our devices is attributed to the amorphous nature of the NiOx produced by the solution-based photodeposition method, which yields a more effective ion storage counter electrode relative to the crystalline NiOx layers that are more widely used. This versatile method yields a distinctive approach for constructing EC windows.

| S-EPMC6277218 | biostudies-literature

Solvation of Na? in the Sodide Solution, LiNa?10MeNH2.

Project description:Alkalides, the alkali metals in their ?1 oxidation state, represent some of the largest and most polarizable atomic species in condensed phases. This study determines the solvation environment around the sodide anion, Na?, in a system of co-solvated Li+. We present isotopically varied total neutron scattering experiments alongside empirical potential structure refinement and ab initio molecular dynamics simulations for the alkali?alkalide system, LiNa?10MeNH2. Both local coordination modes and the intermediate range liquid structure are determined, which demonstrate that distinct structural correlations between cation and anion in the liquid phase extend beyond 8.6 ?. Indeed, the local solvation around Na? is surprisingly well defined with strong solvent orientational order, in contrast to the classical description of alkalide anions not interacting with their environment. The ion-paired Li(MeNH2)4+?Na? species appears to be the dominant alkali?alkalide environment in these liquids, whereby Li+ and Na? share a MeNH2 molecule through the amine group in their primary solvation spheres.

| S-EPMC7007231 | biostudies-literature

Oxidative degradation of reducing carbohydrates to ammonium formate with H(2)O(2) and NH(4)OH.

Project description:Oxidation of various carbohydrates to ammonium formate was investigated in the presence of hydrogen peroxide and ammonium hydroxide. Most of the examined carbohydrates except nonreducing sugars were efficiently converted into ammonium formate under environment friendly and mild conditions in aqueous media.

| S-EPMC2976561 | biostudies-literature

SOLUTION

Project description:Investigation of domestication footprints in three major Solanaceae species

| PRJEB26324 | ENA

Infrared Spectra of Small Radicals for Exoplanetary Spectroscopy: OH, NH, CN and CH: The State of Current Knowledge.

Project description:In this study, we present a current state-of-the-art review of middle-to-near IR emission spectra of four simple astrophysically relevant molecular radicals-OH, NH, CN and CH. The spectra of these radicals were measured by means of time-resolved Fourier transform infrared spectroscopy in the 700-7500 cm-1 spectral range and with 0.07-0.02 cm-1 spectral resolution. The radicals were generated in a glow discharge of gaseous mixtures in a specially designed discharge cell. The spectra of short-lived radicals published here are of great importance, especially for the detailed knowledge and study of the composition of exoplanetary atmospheres in selected new planets. Today, with the help of the James Webb telescope and upcoming studies with the help of Plato and Ariel satellites, when the investigated spectral area is extended into the infrared spectral range, it means that detailed knowledge of the infrared spectra of not only stable molecules but also the spectra of short-lived radicals or ions, is indispensable. This paper follows a simple structure. Each radical is described in a separate chapter, starting with historical and actual theoretical background, continued by our experimental results and concluded by spectral line lists with assigned notation.

| S-EPMC10143568 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data