Ontology highlight
ABSTRACT:
SUBMITTER: Sun J
PROVIDER: S-EPMC2960889 | biostudies-other | 2008
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20080305 Pt 4
THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats. ...[more]