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4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane.

ABSTRACT: THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats.

SUBMITTER: Sun J

PROVIDER: S-EPMC2960889 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane.

Sun Junshan J Huo Yanmin Y Wu Rentao R Li Jikun J Ma Yudao Y

Acta crystallographica. Section E, Structure reports online 20080305 Pt 4

THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats. ...[more]

PMID: 21202048

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