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Di-?-chlorido-bis-{aqua-chlorido[3-ethyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-?N,N]manganese(II)}.

ABSTRACT: In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N'-bidentate ligand, a water mol-ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa-hedral geometry. The Mn?Mn separation is 3.6563?(9)?Å. In the crystal structure, O-H?N and O-H?Cl hydrogen bonds help to establish the packing.

SUBMITTER: Wang Z

PROVIDER: S-EPMC2968385 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Di-μ-chlorido-bis-{aqua-chlorido[3-ethyl-4-phenyl-5-(2-pyrid-yl)-4H-1,2,4-triazole-κN,N]manganese(II)}.

Wang Zuoxiang Z Gong Ixaoning I Liu Chunyi C Zhang Xiaoming X

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

In the centrosymmetric dinuclear title compound, [Mn(2)Cl(4)(C(15)H(14)N(4))(2)(H(2)O)(2)], the Mn(II) atom is coordinated by an N,N'-bidentate ligand, a water mol-ecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN(2)OCl(3) octa-hedral geometry. The Mn⋯Mn separation is 3.6563 (9) Å. In the crystal structure, O-H⋯N and O-H⋯Cl hydrogen bonds help to establish the packing. ...[more]

PMID: 21581769

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