Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-N,N'-Bis(2,6-dimethyl-phen-yl)-N,N'-bis-(trichloro-silyl)ethyl-ene-1,2-diamine.

ABSTRACT: The asymmetric unit of the title compound, C(18)H(20)Cl(6)N(2)Si(2), contains one half of the centrosymmetric mol-ecule. The two benzene rings are perpendicular to the plane of Si-N-C=C-N-Si fragment, making a dihedral angle of 89.9?(1)°. The crystal packing exhibits short inter-molecular Cl?Cl contacts of 3.3119?(17)?Å.

SUBMITTER: Yang W

PROVIDER: S-EPMC2968502 | biostudies-other | 2009

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

(E)-N,N'-Bis(2,6-dimethyl-phen-yl)-N,N'-bis-(trichloro-silyl)ethyl-ene-1,2-diamine.

Yang Wei W Zhang Ming M Liu Guangyan G Ding Yuqiang Y

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

The asymmetric unit of the title compound, C(18)H(20)Cl(6)N(2)Si(2), contains one half of the centrosymmetric mol-ecule. The two benzene rings are perpendicular to the plane of Si-N-C=C-N-Si fragment, making a dihedral angle of 89.9 (1)°. The crystal packing exhibits short inter-molecular Cl⋯Cl contacts of 3.3119 (17) Å. ...[more]

PMID: 21582277

Similar Datasets

Bis(2-amino-4,5-dimethyl-anilinium chloride) 4,5-dimethyl-benz-ene-1,2-diamine monohydrate.

Project description:The title compound, 2C(8)H(13)N(2) (+)·2Cl(-)·C(8)H(12)N(2)·H(2)O, is a hydrated 2:1 cocrystal of the 2-amino-4,5-dimethyl-anilinium chloride salt and the 4,5-dimethyl-benz-ene-1,2-diamine free base. An intra-molecular N-H⋯N hydrogen bond occurs in one of the organic mol-ecules. In the crystal structure, the components are linked by N-H⋯Cl, N-H⋯N, N-H⋯O and O-H⋯Cl hydrogen bonds into a layered motif.

| S-EPMC2977749 | biostudies-literature

N,N'-Bis(2,6-diethyl-phen-yl)acenaphthyl-ene-1,2-diimine.

Project description:The title compound, C(32)H(32)N(2), has crystallographic twofold rotation symmetry, with two C atoms lying on the rotation axis. The dihedral angle between the substituted benzene ring and the naphthalene ring system is 79.8?(1)°. The crystal structure is stabilized by C-H?N inter-actions, which form a chain motif along the b-axis direction.

| S-EPMC3254474 | biostudies-literature

Bis[1,2-bis-(4-chloro-phen-yl)-ethyl-ene-1,2-dithiol-ato(1-)]nickel(II).

Project description:The title compound, [Ni(S2C2(C6H4-p-Cl)2)2] or [Ni(C14H8Cl2S2)2], crystallizes in the triclinic space group P as pairs of mol-ecules disposed about an inversion center at the bc face of the cell. Close inter-molecular C-H⋯S (2.884 Å) and C-H⋯Ni (3.032 Å) contacts that are less than the sum of the van der Waals radii appear to induce slight bowing of the mol-ecular planes toward one another. The angles at which the four p-ClC6H4- rings join the NiS2C2 chelate rings [39.37 (9)- 53.41 (6)°] are similarly influenced by these inter-molecular contacts. In the larger packing arrangement, sheets of mol-ecules extend in the direction of the ac face diagonal.

| S-EPMC9462000 | biostudies-literature

N,N'-Bis[(E)-1-(thio-phen-3-yl)ethyl-idene]ethane-1,2-diamine.

Project description:The complete mol-ecule of the title compound, C(14)H(16)N(2)S(2), is generated by a crystallographic inversion centre. The thio-phene residue is close to being coplanar with the imine group [C-C-C-N torsion angle = 6.5 (2)°], and the conformation about the imine C=N bond [1.281 (2) Å] is E. In the crystal, the three-dimensional architecture is consolidated by C-H⋯N, C-H⋯π and S⋯S [3.3932 (7) Å] inter-actions.

| S-EPMC3343990 | biostudies-literature

1,4-Bis[4-(dimethyl-silyl)phen-yl]benzene.

Project description:The complete molecule of the title compound, C(22)H(26)Si(2), is generated by a crystallographic centre of symmetry. The central benzene ring makes a dihedral angle of 26.7?(4)° with the 4-(dimethyl-silyl)phenyl ring. There are weak C-H?? inter-actions in the crystal structure.

| S-EPMC2984042 | biostudies-literature

[μ-N,N'-Bis(2-pyridylmethyl-ene)ethane-1,2-diamine]bis-{aqua-[N,N'-bis-(2-pyridyl-methyl-ene)ethane-1,2-diamine]manganese(II)} tetra-kis(perchlorate).

Project description:The cation of the salt, [Mn(2)(C(14)H(14)N(4))(3)(H(2)O)(2)](ClO(4))(4), lies on a center of inversion, the center lying midway along the ethyl-ene chain of the bridging N,N'-bis-(2-pyridylmethyl-ene)ethane-1,2-diamine ligand. The Mn atom is chelated by two atoms N atoms of this bridging ligand, and is also coordinated by four N atoms of another ligand. The Mn atom is seven-coordinated in a penta-gonal-bipyramidal environment. The crystal structure displays inter-molecular π-π inter-actions between adjacent pyridine rings, with a shortest centroid-centroid distance of 3.784 (3) Å. The perchlorate is linked to the dinuclear cation by O-H⋯O hydrogen bonds.

| S-EPMC2983616 | biostudies-literature

Bis(acetato-?O)bis-(4,5-dimethyl-benzene-1,2-diamine-?N)zinc.

Project description:The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter-molecular N-H?O hydrogen bonds and intra-molecular N-H?O and N-H?N hydrogen bonding.

| S-EPMC3414110 | biostudies-literature

N,N'-Bis(2,6-dichloro-benzyl-idene)propane-1,2-diamine.

Project description:In the title Schiff base, C(17)H(14)Cl(4)N(2), the atoms of one of the 2,6-dichloro-benzyl-idene units and the central 1,2-diamino-propane grouping are disordered over two sets of sites in a 0.8838 (12):0.1162 (12) ratio. The dihedral angles between the ordered benzene ring and its disordered counterparts are 57.41 (12) and 54.8 (6)° for the major and minor disorder components, respectively. The crystal studied was a racemic twin, the refined ratio of the twin components being 0.37 (5):0.63 (5).

| S-EPMC2983987 | biostudies-literature

{N',N''-Bis[2,6-bis-(1-methyl-ethyl)phen-yl]-N,N-dimethyl-guanidinato-κN',N''}dibromido-borane.

Project description:In the mol-ecular structure of the title compound, C(27)H(40)N(3)BBr(2), the B atom is connected to two bromide substituents and a guanidinate scaffold, forming a four-membered ring. An aryl group is connected to each N atom in the ring that contains two isopropyl groups in positions 2 and 6.

| S-EPMC2983591 | biostudies-literature

Di-?-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}.

Project description:In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719?(3) and 0.281?(3). Weak C-H?? inter-actions feature in the crystal packing.

| S-EPMC3344410 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data