Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Di-?-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}.

ABSTRACT: In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719?(3) and 0.281?(3). Weak C-H?? inter-actions feature in the crystal packing.

SUBMITTER: Goh C

PROVIDER: S-EPMC3344410 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Di-μ-bromido-bis-{[N,N-dimethyl-N'-(thio-phen-2-yl-methyl-idene)ethane-1,2-diamine]-copper(I)]}.

Goh Christopher C Remillard Zachary D ZD Martinez Andre P AP Keeley Amanda C AC Jasinski Jerry P JP

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

In the crystal structure of the title compound, [Cu(2)Br(2)(C(9)H(14)N(2)S)(2)], the mol-ecule resides about a crystallographic inversion center. The coordination sphere around each copper ion has a distorted tetra-hedral geometry, with ligation by two bridging bromide ions, an amine N atom and an imine N atom. The thio-phene ring is disordered over two sites, with occupancies of 0.719 (3) and 0.281 (3). Weak C-H⋯π inter-actions feature in the crystal packing. ...[more]

PMID: 22590172

Similar Datasets

Bromido{N-methyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-(thio-cyanato-?N)-copper(II).

Project description:In the title mononuclear copper(II) compound, [CuBr(NCS)(C(10)H(15)N(3))], the Cu(II) atom is five-coordinated by three N atoms of the Schiff base ligand, the N atom of a thio-cyanate ligand and by one bromide ion forming a distorted square-pyramidal geometry. In the crystal structure, mol-ecules are linked through inter-molecular N-H?Br hydrogen bonds into chains propagating along [101].

| S-EPMC3007341 | biostudies-literature

N,N'-Bis[(E)-1-(thio-phen-3-yl)ethyl-idene]ethane-1,2-diamine.

Project description:The complete mol-ecule of the title compound, C(14)H(16)N(2)S(2), is generated by a crystallographic inversion centre. The thio-phene residue is close to being coplanar with the imine group [C-C-C-N torsion angle = 6.5 (2)°], and the conformation about the imine C=N bond [1.281 (2) Å] is E. In the crystal, the three-dimensional architecture is consolidated by C-H⋯N, C-H⋯π and S⋯S [3.3932 (7) Å] inter-actions.

| S-EPMC3343990 | biostudies-literature

Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}copper(II).

Project description:In the title compound, [CuCl(2)(C(11)H(17)N(3))], the Cu(II) ion is five-coordinated with a distorted square-pyramidal configuration. The three N atoms of the Schiff base ligand and one Cl atom are located in the basal plane, whereas the other Cl atom is apically positioned.

| S-EPMC2979170 | biostudies-literature

Dichlorido{N-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine}copper(II).

Project description:The title complex, [CuCl(2)(C(9)H(13)N(3))], is mononuclear and contains a five-coordinate Cu(II) atom. The geometry of the Cu(II) atom can be described as tetra-gonal-pyramidal derived from the calculation of the value τ = 0.102. The three N atoms of the pyridine and ethane-1,2-diamine ligands and one Cl atom belong to the basal plane and the other Cl atom represents the axial position of the pyramid. The Cu atom is displaced by 0.2599 (2) Å from the basal plane towards the axial Cl atom. In the crystal, mol-ecules are linked into chains by inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds.

| S-EPMC2968900 | biostudies-literature

Diiodido[N'-(2-methoxy-benzyl-idene)-N,N-dimethyl-ethane-1,2-diamine]zinc(II).

Project description:In the title complex, [Zn(C(12)H(18)N(2)O)I(2)], the Zn(II) ion is four-coordinated by the imine N and amine N atoms of the Schiff base ligand and by two iodide ions in a distorted tetra-hedral coordination.

| S-EPMC2970288 | biostudies-literature

catena-Poly[[{N,N-dimethyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}(thio-cyanato-?N)cadmium]-?-thio-cyanato-?S:N].

Project description:In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octa-hedrally coordinated by the N,N',N''-tridentate Schiff base ligand and one terminal thio-cyanate N atom. Two trans-N:S-bridging thio-cyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thio-cyanate N:S-bridges into polymeric chains along the c axis.

| S-EPMC3099776 | biostudies-literature

{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}bis-(thio-cyanato-?N)copper(II).

Project description:The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter-molecular C-H?S and C-H?N hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. Intra-molecular C-H?N inter-actions are also observed.

| S-EPMC3151817 | biostudies-other

Aqua-{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Project description:In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H⋯π inter-actions. The -CH(2)-N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio.

| S-EPMC3099768 | biostudies-literature

Tris(ethane-1,2-diamine)copper(II) bis-(trifluoro-acetate).

Project description:In the title complex, [Cu(H(2)NCH(2)CH(2)NH(2))(3)](CF(3)COO)(2), the environment of the Cu atom is distorted octa-hedral, formed by six N atoms from three chelating ethane-1,2-diamine ligands. The Cu-N distances range from 2.050 (2) to 2.300 (2) Å. This complex cation and the two trifluoro-acetate anions are connected by weak N-H⋯O and N-H⋯F hydrogen bonds, forming a three-dimensional framework. In both anions, the F atoms are disordered over two positions; in one the site-occupancy factors are 0.55 and 0.45, in the other the values are 0.69 and 0.31.

| S-EPMC2960438 | biostudies-literature

trans-Bis[1,2-bis-(dimethyl-phosphino)-ethane]-bromido-nitrosyl-tungsten(0).

Project description:The crystal structure of the title compound, [WBr(NO)(C(6)H(16)P(2))(2)], reveals a distorted octa-hedral geometry around the W centre. The W atom lies on a special position at an inversion centre (the Br and NO ligands are equally disordered). The bis-(dimethyl-phosphino)ethane ligand is also severely disordered (site occupancy factors 0.52 and 0.48). This is the first structure of a tungsten species with nitrosyl and bromide ligands.

| S-EPMC2915161 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data