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(Z)-1,2:5,6-Di-O-isopropyl-idene-?-d-ribo-hexofuranos-3-ulose O-benzyl-oxime.

ABSTRACT: The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl-oxime substituent and the 5,6-O-isopropyl-idene acetal are both located on the Si-face of the C=N double bond. Inter-molecular C-H?O inter-actions result in helical chains along the b axis of the monoclinic unit cell.

SUBMITTER: Burkhardt A

PROVIDER: S-EPMC2968566 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(Z)-1,2:5,6-Di-O-isopropyl-idene-α-d-ribo-hexofuranos-3-ulose O-benzyl-oxime.

Burkhardt Anja A Eriksson Lars L Widmalm Göran G Cumpstey Ian I

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl-oxime substituent and the 5,6-O-isopropyl-idene acetal are both located on the Si-face of the C=N double bond. Inter-molecular C-H⋯O inter-actions result in helical chains along the b axis of the monoclinic unit cell. ...[more]

PMID: 21582282

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