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(E)-N'-(4-Bromo-benzyl-idene)-p-toluene-sulfonohydrazide.

ABSTRACT: In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, inter-molecular N-H?O and C-H?O hydrogen bonds link neighbouring mol-ecules into different dimers along the b axis, generating R(2) (2)(8) and R(2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82.39?(13)°. The crystal structure is further stabilized by inter-molecular ?-? stacking inter-actions [centroid-centroid distances = 3.867?(2)-3.9548?(8)?Å].

SUBMITTER: Kia R 

PROVIDER: S-EPMC2968802 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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(E)-N'-(4-Bromo-benzyl-idene)-p-toluene-sulfonohydrazide.

Kia Reza R   Etemadi Bijan B   Fun Hoong-Kun HK   Kargar Hadi H  

Acta crystallographica. Section E, Structure reports online 20090325 Pt 4

In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link neighbouring mol-ecules into different dimers along the b axis, generating R(2) (2)(8) and R(2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82.39 (13)°. The crystal structure is further stabilized by inter-molecular π-π stacking inter-actions [centroid-centroid distances = 3.867 (2)-3.9548 (8) Å]. ...[more]

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