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(E)-N'-Benzyl-idene-p-toluene-sulfono-hydrazide.

ABSTRACT: In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra-molecular C-H?O hydrogen bond generates an S(5) ring motif. The mol-ecule adopts a twisted E configuration around the C=N bond. An inter-molecular N-H?O hydrogen bond generates an R(2) (2)(8) ring motif. The dihedral angle between the rings is 85.37?(9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, inter-molecular N-H?O hydrogen bonds link neighbouring mol-ecules into dimers which stack along the a axis with a centroid-centroid distance of 3.8856?(10)?Å.

SUBMITTER: Mehrabi H

PROVIDER: S-EPMC2960482 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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(E)-N'-Benzyl-idene-p-toluene-sulfono-hydrazide.

Mehrabi Hossein H Kia Reza R Hassanzadeh Ali A Ghobadi Samaneh S Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9

In the title compound, C(14)H(14)N(2)O(2)S, a novel sulfonamide derivative, an intra-molecular C-H⋯O hydrogen bond generates an S(5) ring motif. The mol-ecule adopts a twisted E configuration around the C=N bond. An inter-molecular N-H⋯O hydrogen bond generates an R(2) (2)(8) ring motif. The dihedral angle between the rings is 85.37 (9)°. The H atoms of the methyl group have rotational disorder with refined site occupancies of ca 0.63/0.37. In the crystal structure, inter-molecular N-H⋯O hydroge ...[more]

PMID: 21201816

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