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N-(2-Ferrocenylethyl-idene)-4-(trifluoro-meth-yl)aniline.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro-meth-yl)aniline. The cyclo-penta-dienyl (Cp) rings are coplanar [dihedral angle = 1.4?(3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5?(4)°. The F atoms of the trifluoro-methyl substituent are disordered [occupancies 0.52?(2)/0.48?(2)].

SUBMITTER: Imhof W

PROVIDER: S-EPMC2969081 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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N-(2-Ferrocenylethyl-idene)-4-(trifluoro-meth-yl)aniline.

Imhof Wolfgang W

Acta crystallographica. Section E, Structure reports online 20090328 Pt 4

The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro-meth-yl)aniline. The cyclo-penta-dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°. The F atoms of the trifluoro-methyl substituent are disordered [occupancies 0.52 (2)/0.48 (2)]. ...[more]

PMID: 21582394

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