Ontology highlight
ABSTRACT:
SUBMITTER: Li YF
PROVIDER: S-EPMC2969083 | biostudies-other | 2009
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20090306 Pt 4
The title compound, C(20)H(25)NO(4), was synthesized by a Mitsunobu reaction of sinomenine [(9S,13R,14R)-7,8-didehydro-4-hydroxy-3,7-dimethoxy-17-methylmorphinan-6-one] with methanol. The chiral centers were unchanged during the reaction. Intra-molecular C-H⋯O hydrogen bonds result in the formation of six-membered rings. ...[more]