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(8S,9S,10R)-4-(4-Chloro-benz-yloxy)-7,8-didehydro-3,7-dimeth-oxy-17-methyl-morphinan-6-one monohydrate.

ABSTRACT: In the title compound, C(26)H(28)Cl(N)O(4)·H(2)O, the dihedral angle betwene the two aromatic rings is 69.73?(6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water mol-ecule forms O-H?O and O-H?N hydrogen bonds and a C-H?O link also occurs.

SUBMITTER: Zheng XL

PROVIDER: S-EPMC3089213 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(8S,9S,10R)-4-(4-Chloro-benz-yloxy)-7,8-didehydro-3,7-dimeth-oxy-17-methyl-morphinan-6-one monohydrate.

Zheng Xing-Liang XL Chen Shu-Jun SJ Jiang Ning-Fei NF Zhan Sue-Hui SH

Acta crystallographica. Section E, Structure reports online 20110422 Pt 5

In the title compound, C(26)H(28)Cl(N)O(4)·H(2)O, the dihedral angle betwene the two aromatic rings is 69.73 (6)°. The N-containing ring exhibits a chair conformation, while the other non-aromatic rings are in approximate envelope conformations. In the crystal, the water mol-ecule forms O-H⋯O and O-H⋯N hydrogen bonds and a C-H⋯O link also occurs. ...[more]

PMID: 21754492

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