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Trans-Bis(4,6-dimethyl-pyrimidine-2-thiol-ato-?N,S)bis-(thio-urea-?S)nickel(II).

ABSTRACT: In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl-pyrimidine-2-thiol-ate ligands and two trans S-coordinating thio-urea groups. The trans-N(2)S(4) donor set defines a distorted octa-hedral geometry.

SUBMITTER: Zhu J

PROVIDER: S-EPMC2971843 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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trans-Bis(4,6-dimethyl-pyrimidine-2-thiol-ato-κN,S)bis-(thio-urea-κS)nickel(II).

Zhu Jing J Wang Jian-Gang JG Duan Taike T Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

In the title complex, [Ni(C(6)H(7)N(2)S)(2)(CH(4)N(2)S)(2)], the central Ni atom (located on a centre of inversion) is six-coordinated by two monoanionic N,S-chelating 4,6-dimethyl-pyrimidine-2-thiol-ate ligands and two trans S-coordinating thio-urea groups. The trans-N(2)S(4) donor set defines a distorted octa-hedral geometry. ...[more]

PMID: 21578701

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