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Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-?-bromido-dibromido-plumbate(II)]].

ABSTRACT: The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic-organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa-hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa-hedra and the organic cation exhibit symmetry. The cations inter-act via N-H?Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.

SUBMITTER: Rayner MK

PROVIDER: S-EPMC2979491 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-μ-bromido-dibromido-plumbate(II)]].

Rayner Matthew Kyle MK Billing David Gordon DG

Acta crystallographica. Section E, Structure reports online 20100515 Pt 6

The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic-organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa-hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa-hedra and the organic cation exhibit symmetry. The cations inter-act via N-H⋯Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif. ...[more]

PMID: 21579303

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