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2,4-Dichloro-6-(8-quinolylamino-methyl-ene)cyclo-hexa-2,4-dien-1-one methanol solvate.

ABSTRACT: The main mol-ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N-H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17?(3)°. A bifurcated intra-molecular N-H?(O,N) hydrogen bond is present as well as an O-H?O hydrogen bond. In the crystal, C-H?O inter-actions link the 3,5-dichloro-salicyl-idene-8-amino-quinoline and methanol mol-ecules.

SUBMITTER: Shibahara T

PROVIDER: S-EPMC2979828 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2,4-Dichloro-6-(8-quinolylamino-methyl-ene)cyclo-hexa-2,4-dien-1-one methanol solvate.

Shibahara Takashi T Takahashi Masayuki M Maekawa Atsushi A Takagi Hideaki H

Acta crystallographica. Section E, Structure reports online 20100123 Pt 2

The main mol-ecule of the title methanol solvate, C(16)H(10)Cl(2)N(2)O·CH(3)OH, exists in the keto form and the C=O and N-H bonds are mutually cis in the crystal structure. The dihedral angle between the quinoline and benzene rings is 11.17 (3)°. A bifurcated intra-molecular N-H⋯(O,N) hydrogen bond is present as well as an O-H⋯O hydrogen bond. In the crystal, C-H⋯O inter-actions link the 3,5-dichloro-salicyl-idene-8-amino-quinoline and methanol mol-ecules. ...[more]

PMID: 21579844

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