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[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(?-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.

ABSTRACT: In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130?(7) and 2.2231?(7)?Å], a chloride anion [Fe-Cl = 2.3329?(7)?Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732?(3)?Å] in a typical piano-stool geometry. In the crystal structure, the complex and solvent mol-ecules are paired via weak C-H?Cl inter-actions.

SUBMITTER: Ou YP

PROVIDER: S-EPMC3007507 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(η-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.

Ou Ya-Ping YP Feng Dan D Yuan Jing-Jing JJ

Acta crystallographica. Section E, Structure reports online 20100710 Pt 8

In the title compound, [Fe(C(10)H(15))Cl(C(26)H(24)P(2))]·CH(2)Cl(2), the Fe(II) atom is coordinated by two P atoms from a 1,2-bis-(diphenyl-phosphino)ethane ligand [Fe-P = 2.2130 (7) and 2.2231 (7) Å], a chloride anion [Fe-Cl = 2.3329 (7) Å] and a penta-methyl-cyclo-penta-dienyl (Cp*) ligand [Fe-centroid(Cp*) = 1.732 (3) Å] in a typical piano-stool geometry. In the crystal structure, the complex and solvent mol-ecules are paired via weak C-H⋯Cl inter-actions. ...[more]

PMID: 21588156

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