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2-[(2,6-Dichloro-benz-yl)amino]-N-(4-methyl-thia-zol-2-yl)acetamide.

ABSTRACT: In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia-zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08?(2)°] because the N-C-C-N-C chain that links the two rings is folded [N-C-C-N torsion angle = 12.0?(2)°] rather than fully extended. An intra-molecular N-H?N inter-action occurs. In the crystal, weak inter-molecular N-H?N and C-H?O inter-actions are present and ?-? inter-actions are indicated by the short distances [3.507?(3)-3.665?(2)?Å] between the centroids of the thia-zole and benzene rings.

SUBMITTER: Luo J 

PROVIDER: S-EPMC2983532 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2-[(2,6-Dichloro-benz-yl)amino]-N-(4-methyl-thia-zol-2-yl)acetamide.

Luo Jie J   Zhao Gui-Long GL   Shao Hua H   Wang Yu-Li YL   Qu Bao-Han BH  

Acta crystallographica. Section E, Structure reports online 20100203 Pt 3

In the title compound, C(13)H(13)Cl(2)N(3)OS, the thia-zole and benzene rings are roughly parallel to one another in two layers [dihedral angle = 5.08 (2)°] because the N-C-C-N-C chain that links the two rings is folded [N-C-C-N torsion angle = 12.0 (2)°] rather than fully extended. An intra-molecular N-H⋯N inter-action occurs. In the crystal, weak inter-molecular N-H⋯N and C-H⋯O inter-actions are present and π-π inter-actions are indicated by the short distances [3.507 (3)-3.665 (2) Å] between  ...[more]

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