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Benzene-1,3,5-triyl tris-(methane-sulfonate).

ABSTRACT: In the mol-ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C-O-S angle range is 119.3?(2)-121.1?(2)°. This conformation is different from that of the benzene analog 1,2,5-tris-(p-toluene-sulfonate), which is a three-legged 'table' with all fragments of the p-toluene-sulfonate on top of the benzene ring. In the crystal, the supra-molecular aggregation is completed by the presence of C-H?O hydrogen bonds.

SUBMITTER: Madrigal D

PROVIDER: S-EPMC2983843 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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Benzene-1,3,5-triyl tris-(methane-sulfonate).

Madrigal Domingo D Aguirre Gerardo G Vargas Berenice B

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

In the mol-ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C-O-S angle range is 119.3 (2)-121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris-(p-toluene-sulfonate), which is a three-legged 'table' with all fragments of the p-toluene-sulfonate on top of the benzene ring. In the crystal, the supra-molecular aggregation is completed by the presence of C-H⋯O hydrogen bonds. ...[more]

PMID: 21580584

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