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Tert-Butyl 2-[4-(2-{4-[(tert-butoxycar-bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate.

ABSTRACT: In the mol-ecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(ar-yl)-C-C(ar-yl) angle to 111.5?(1)°. The four-atom -O-CH(2)-C(=O)-O- linkage between the aromatic ring and the tert-butyl group assumes a (-)anti-periplanar conformation for one substituent and a (-)syn-periplanar conformation for the other substituent; the O-C-C-O torsion angles are -173.7?(2) and -10.2?(3)°.

SUBMITTER: Ali Q

PROVIDER: S-EPMC3006808 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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tert-Butyl 2-[4-(2-{4-[(tert-butoxycar-bonyl)methoxy]-3-methylphenyl}-2-propyl)-2-methylphenoxy]acetate.

Ali Qamar Q Yousuf Sammer S Raza Shah Muhammad M Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100623 Pt 7

In the mol-ecule of the title compound, C(29)H(40)O(6), the carbon atom belonging to the propyl chain is connected to two aromatic rings that open up the C(ar-yl)-C-C(ar-yl) angle to 111.5 (1)°. The four-atom -O-CH(2)-C(=O)-O- linkage between the aromatic ring and the tert-butyl group assumes a (-)anti-periplanar conformation for one substituent and a (-)syn-periplanar conformation for the other substituent; the O-C-C-O torsion angles are -173.7 (2) and -10.2 (3)°. ...[more]

PMID: 21587966

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