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5,8-Dibromo-2,11-dithia-[3,3](2,6)pyridino-paracyclo-phane.

ABSTRACT: The title compound, C(15)H(13)Br(2)NS(2) [systematic name: 1(2),1(5)-dibromo-2,7-dithia-1(1,4)-benzena-5(2,6)-pyridinaocta-phane], contains a dibromo-substituted benzene ring and a pyridine ring that are linked by a pair of bridging -CH(2)SCH(2)- groups. There is a weak ?-? inter-action between the rings, the distance between the ring centroids being 3.572?(4)?Å. The rings are not parallel, but form a dihedral angle of 18.29?(4)°.

SUBMITTER: Li SS

PROVIDER: S-EPMC3007406 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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5,8-Dibromo-2,11-dithia-[3,3](2,6)pyridino-paracyclo-phane.

Li Si-Si SS Zhang Bei B Zhang Hong-Lin HL

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

The title compound, C(15)H(13)Br(2)NS(2) [systematic name: 1(2),1(5)-dibromo-2,7-dithia-1(1,4)-benzena-5(2,6)-pyridinaocta-phane], contains a dibromo-substituted benzene ring and a pyridine ring that are linked by a pair of bridging -CH(2)SCH(2)- groups. There is a weak π-π inter-action between the rings, the distance between the ring centroids being 3.572 (4) Å. The rings are not parallel, but form a dihedral angle of 18.29 (4)°. ...[more]

PMID: 21588414

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