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2-Chloro-N-isopropyl-N-phenyl-acetamide.

ABSTRACT: In the title compound, C(11)H(14)ClNO, the herbicide propachlor, there are significant differences between the three N-C bond lengths [N-C(carbon-yl) = 1.354?(3)?Å, N-C(phen-yl) = 1.444?(2)?Å and N-C(isoprop-yl) = 1.496?(3)?Å], indicating the presence of ? delocalization involving the carbonyl group. The N atom lies 0.074?(2)?Å from the plane defined by the the three bonded C atoms.

SUBMITTER: Yuan MS

PROVIDER: S-EPMC3007416 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2-Chloro-N-isopropyl-N-phenyl-acetamide.

Yuan Mao-Sen MS Li Zhi-Peng ZP Wang Qi Q

Acta crystallographica. Section E, Structure reports online 20100714 Pt 8

In the title compound, C(11)H(14)ClNO, the herbicide propachlor, there are significant differences between the three N-C bond lengths [N-C(carbon-yl) = 1.354 (3) Å, N-C(phen-yl) = 1.444 (2) Å and N-C(isoprop-yl) = 1.496 (3) Å], indicating the presence of π delocalization involving the carbonyl group. The N atom lies 0.074 (2) Å from the plane defined by the the three bonded C atoms. ...[more]

PMID: 21588328

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