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(E)-Methyl 3-(3,5-dibromo-2-hy-droxy-benzyl-idene)carbazate.

ABSTRACT: The title compound, C(9)H(8)Br(2)N(2)O(3), crystallizes with two very similar independent mol-ecules in the asymmetric unit, each of which adopts a trans configuration with respect to the C=N bond. Intra-molecular O-H?N hydrogen bonds are observed in each independent mol-ecule. In the crystal structure, mol-ecules are linked into chains propagating along [010] by N-H?O and C-H?O hydrogen bonds. In addition, C-H?? inter-actions stabilize the structure.

SUBMITTER: Lv LP

PROVIDER: S-EPMC3007842 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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(E)-Methyl 3-(3,5-dibromo-2-hy-droxy-benzyl-idene)carbazate.

Lv Lu-Ping LP Liu Songhui S

Acta crystallographica. Section E, Structure reports online 20100828 Pt 9

The title compound, C(9)H(8)Br(2)N(2)O(3), crystallizes with two very similar independent mol-ecules in the asymmetric unit, each of which adopts a trans configuration with respect to the C=N bond. Intra-molecular O-H⋯N hydrogen bonds are observed in each independent mol-ecule. In the crystal structure, mol-ecules are linked into chains propagating along [010] by N-H⋯O and C-H⋯O hydrogen bonds. In addition, C-H⋯π inter-actions stabilize the structure. ...[more]

PMID: 21588736

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