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4,6-Dibromo-2-[(E)-(4-{[(E)-3,5-dibromo-2-hy-droxy-benzyl-idene]amino}-butyl)-imino-meth-yl]phenol.


ABSTRACT: The asymmetric unit of the title compound, C(18)H(16)Br(4)N(2)O(2), comprises half the molecule, which is located adjacent to an inversion centre at the mid-point of the central C-C bond of the butane-1,4-diamine segment. There are two intra-molecular O-H?N hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-H?Br inter-actions into chains along [101], which include R(2) (2)(8) ring motifs. These chains are further linked by C-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Kargar H 

PROVIDER: S-EPMC3394053 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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4,6-Dibromo-2-[(E)-(4-{[(E)-3,5-dibromo-2-hy-droxy-benzyl-idene]amino}-butyl)-imino-meth-yl]phenol.

Kargar Hadi H   Kia Reza R   Adabi Ardakani Amir A   Tahir Muhammad Nawaz MN  

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7


The asymmetric unit of the title compound, C(18)H(16)Br(4)N(2)O(2), comprises half the molecule, which is located adjacent to an inversion centre at the mid-point of the central C-C bond of the butane-1,4-diamine segment. There are two intra-molecular O-H⋯N hydrogen bonds making S(6) ring motifs. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Br inter-actions into chains along [101], which include R(2) (2)(8) ring motifs. These chains are further linked by C-H⋯O hydrogen bonds, formi  ...[more]

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