Ontology highlight
ABSTRACT:
SUBMITTER: Jones PG
PROVIDER: S-EPMC3007894 | biostudies-other | 2010 Aug
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20100811 Pt 9
In the title compound, [Ir(C(13)H(9)N(4))(C(13)H(8)NS)(2)]·3.5CDCl(3), the coordination at iridium is octa-hedral, but with narrow ligand bite angles. The bond lengths at iridium show the expected trans influence, with the Ir-N bonds trans to C being appreciably longer than those trans to N. The chelate rings are mutually perpendicular, the inter-planar angles between them all lying within 6° of 90°. All ligands are approximately planar; the maximum inter-planar angles within ligands are ca 10°. ...[more]