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[1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III).

ABSTRACT: In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra-hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37?(2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom.

SUBMITTER: Li H

PROVIDER: S-EPMC3011549 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III).

Li Haoyang H Xiang Yonggang Y Han Hongfei H

Acta crystallographica. Section E, Structure reports online 20101120 Pt 12

In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra-hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom. ...[more]

PMID: 21589280

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