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2,5-Bis{2,2-bis-[4-(dimethyl-amino)-phen-yl]ethen-yl}-N,N'-diphenyl-N,N'-dipropyl-benzene-1,4-diamine.


ABSTRACT: The title compound, C(60)H(68)N(6), was prepared by Horner olefination of a terephthaldialdehyde and a diaryl-methyl phospho-nate. There is one half-mol-ecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinyl-ene unit and the central ring is 36.79?(15)°, while those between the vinyl-ene unit and the lateral phenyl rings are 53.04?(10) and 53.74?(9)°.

SUBMITTER: Schmitt V 

PROVIDER: S-EPMC3099848 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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2,5-Bis{2,2-bis-[4-(dimethyl-amino)-phen-yl]ethen-yl}-N,N'-diphenyl-N,N'-dipropyl-benzene-1,4-diamine.

Schmitt Volker V   Schollmeyer Dieter D   Detert Heiner H  

Acta crystallographica. Section E, Structure reports online 20110312 Pt 4


The title compound, C(60)H(68)N(6), was prepared by Horner olefination of a terephthaldialdehyde and a diaryl-methyl phospho-nate. There is one half-mol-ecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinyl-ene unit and the central ring is 36.79 (15)°, while those between the vinyl-ene unit and the lateral phenyl rings are 53.04 (10) and 53.74 (9)°. ...[more]

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