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[?-N,N'-Bis(diphenyl-phosphinometh-yl)benzene-1,4-diamine-?P:P']bis-[(2,2'-bipyridine-?N,N')silver(I)] bis-(per-chlorate) acetone disolvate.

ABSTRACT: The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.

SUBMITTER: Gui LC

PROVIDER: S-EPMC2977627 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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[μ-N,N'-Bis(diphenyl-phosphinometh-yl)benzene-1,4-diamine-κP:P']bis-[(2,2'-bipyridine-κN,N')silver(I)] bis-(per-chlorate) acetone disolvate.

Gui Liu-Cheng LC Ni Qing-Ling QL Jiang Xuan-Feng XF Zeng Jian-Qiang JQ Wang Xiu-Jian XJ

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment. ...[more]

PMID: 21583813

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