Browse
Submit Data
Databases
API
Help

Dataset Information

18 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[?-N,N'-Bis(diphenyl-phosphinometh-yl)benzene-1,4-diamine-?P:P']bis-[(2,2'-bipyridine-?N,N')silver(I)] bis-(per-chlorate) acetone disolvate.

ABSTRACT: The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment.

SUBMITTER: Gui LC

PROVIDER: S-EPMC2977627 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[μ-N,N'-Bis(diphenyl-phosphinometh-yl)benzene-1,4-diamine-κP:P']bis-[(2,2'-bipyridine-κN,N')silver(I)] bis-(per-chlorate) acetone disolvate.

Gui Liu-Cheng LC Ni Qing-Ling QL Jiang Xuan-Feng XF Zeng Jian-Qiang JQ Wang Xiu-Jian XJ

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The title complex, [Ag(2)(C(10)H(8)N(2))(2)(C(32)H(30)N(2)P(2))](ClO(4))(2)·2CH(3)COCH(3), is a centrosymmetric dimer with pairs of Ag(I) atoms bridged by N,N'-bis-(diphenyl-phosphinometh-yl)ben-zene-1,4-diamine ligands. In addition, each Ag(I) atom is coordin-ated by one chelating 2,2'-bipyridine ligand, giving a distorted trigonal coordination environment. ...[more]

PMID: 21583813

Similar Datasets

(2,2'-Bipyridine-?(2) N,N')[bis-(diphenyl-thio-phosphino-yl)meth-yl]lithium(I) benzene monosolvate.

Project description:In the title benzene-solvated heteroleptic lithium complex, [Li(C25H21P2S2)(C10H8N2)]·C6H6, the Li(I) ion is four-coordinated in a distorted tetra-hedral geometry by two S atoms and two N atoms of the two chelating ligands, viz. bis-(diphenyl-thio-phosphino-yl)methyl and 2,2'-bipyridine. The 2,2'-bipyridine mol-ecule is slightly twisted with a dihedral angle between the pyridine rings of 7.35?(12)°. Intra-molecular C-H?S hydrogen bonds are present. In the crystal, mol-ecules are stacked along the c axis by ?-? inter-actions, with centroid-centroid distances of 3.6021?(15) and 3.6401?(16)?Å. The crystal structure also features weak C-H?? inter-actions.

| S-EPMC3588425 | biostudies-literature

?-1,2-Bis-(diphenyl-phos-phino)-ethane-?P:P'-bis-{[1,2-bis-(diphenyl-phosphino)-ethane-?P,P']bromidocopper(I)} acetone disolvate.

Project description:In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the methyl-ene C atoms of the bridging dppe ligand. The crystal structure is stabilized by intra-molecular C-H?Br hydrogen bonds and inter-molecular ?-? inter-actions, with a centroid-to-centroid distance of 3.2055?(1)?Å.

| S-EPMC2959431 | biostudies-literature

Bis(2,2'-bipyridine)(2-hy-droxy-2,2-diphenyl-acetato)-copper(II) nitrate dihydrate.

Project description:In the title complex, [Cu(C(14)H(11)O(3))(C(10)H(8)N(2))(2)]NO(3)·2H(2)O, the Cu(II) atom is coordinated by four N atoms from two 2,2'-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octa-hedral geometry. A supra-molecular network is formed via inter-molecular O-H?O and C-H?O hydrogen-bonding inter-actions. ?-? stacking inter-actions between neighboring pyridine rings are also present, the centroid-centroid distance being 3.808?(2)?Å.

| S-EPMC2983227 | biostudies-literature

5,5'-Bis[(1H-imidazol-1-yl)meth-yl]-2,2'-bipyridine methanol disolvate.

Project description:The title compound, C(18)H(16)N(6)·2CH(3)OH, was prepared by the reaction of 5,5'-bis-(bromo-meth-yl)-2,2'-bipyridine with imidazole. The main mol-ecule lies on an inversion center located at the mid-point of the C-C bond joining the two pyridine rings. The asymmetric unit therefore contains one half-mol-ecule and one methanol solvent mol-ecule. The dihedral angle between the pyridine and imidazole rings is 72.32 (5)°. In the crystal, weak inter-molecular O-H⋯N, C-H⋯N and C-H⋯O hydrogen bonds contribute to the stabilization of the packing.

| S-EPMC3051999 | biostudies-literature

{?-N,N,N',N'-Tetra-kis[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine}-bis-[(2,2'-bipyrid-yl)copper(I)] bis-(tetra-fluoridoborate).

Project description:In the title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(58)H(52)N(2)P(4))](BF(4))(2), the dinuclear cation lies on an inversion centre. The Cu(I) atom is coordinated by two N atoms from a 2,2'-bipyridine ligand and two P atoms from an N,N,N',N'-tetra-kis-[(diphenyl-phos-phan-yl)meth-yl]benzene-1,4-diamine ligand in a distorted tetra-hedral geometry. In the crystal, inter-molecular C-H?F hydrogen bonds link the ions into layers parallel to [[Formula: see text]01]. ?-? inter-actions [centroid-centroid distance = 3.668?(4)?Å] are also observed. One F atom of the anion is disordered over two orientations with a refined occupancy ratio of 0.675?(13):0.325?(13).

| S-EPMC3212203 | biostudies-literature

Bis(2,2'-bipyridine)bis-{μ(3)-cis-N-(2-carboxyl-atophen-yl)-N'-[3-(dimethyl-amino)prop-yl]oxamidato(3-)}-bis(per-chlorato)-tetra-nickel(II) methanol disolvate.

Project description:In the title methanol disolvate complex, [Ni(4)(C(14)H(16)N(3)O(4))(2)(ClO(4))(2)(C(10)H(8)N(2))(2)]·2CH(3)OH, the neutral tetra-nickel(II) system lies on a centre of inversion. The polyhedron around each Ni(II) atom is a square pyramid. The separations of the Ni atoms bridged by the oxamide and carboxyl groups are 5.227 (9) and 5.268 (6) Å, respectively. In the crystal structure, a two-dimensional supramolecular network structure involving O-H⋯O and C-H⋯O hydrogen bonding is observed.

| S-EPMC2971995 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl-?N)benzene-sulfonamidato-?N](4,4'-di-methyl-2,2'-bipyridine-?N,N')cadmium dimethyl-formamide disolvate.

Project description:In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-formamide mol-ecule show disorder and were modelled with two different orientations and with site occupancies of 0.584?(10):0.416?(10). The geometry around the sulfadiazine S atom is distorted tetra-hedral. The crystal structure involves N-H?O hydrogen bonds which link mol-ecules into a three-dimensional network. Weak C-H?O hydrogen bonds are also observed.

| S-EPMC3297235 | biostudies-literature

Bis[?-bis-(diphenyl-phosphino)methane-?P:P']bis-[(2,2'-bipyridine-?N,N')copper(I)] bis-(tetra-fluoro-borate).

Project description:The centrosymmetric title compound, [Cu(2)(C(10)H(8)N(2))(2)(C(25)H(22)P(2))(2)](BF(4))(2), consists of discrete dinuclear cations and tetra-fluoro-borate anions. The two Cu(I) centers are bridged by the phosphine ligands to form an eight-membered ring. The Cu(I) center exhibits a tetra-hedral coordination as it is chelated by the N-heterocycle.

| S-EPMC2970481 | biostudies-literature

{?-N,N'-Bis[1-(2-pyridyl)ethylidene]benzene-1,2-diamine}di-?-chlorido-bis[diaquanickel(II)] dichloride ethanol disolvate.

Project description:In the title compound, [Ni(2)Cl(2)(C(20)H(18)N(4))(H(2)O)(4)]Cl(2)·2C(2)H(6)O, the coordination environment of each Ni(2+) ion is distorted octa-hedral formed by two N atoms from the Schiff base ligand, two O atoms from water mol-ecules and two chloride anions acting as ?(2) bridges between the metal ions. The coordinated water mol-ecules are linked to the uncoordinated ethanol mol-ecules and chloride anions by O-H?O and O-H?Cl hydrogen bonds, although the assignment of some of these is tentative. A weak inter-molecular O-H?N inter-action within the ligand is also observed.

| S-EPMC2968006 | biostudies-literature

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](2,2'-bipyridine)manganese(II).

Project description:The title compound, [Mn(C(10)H(9)N(4)O(2)S)(2)(C(10)H(8)N(2))], contains a distorted octa-hedral [Mn(sdz)(2)(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2'-bipyridine) complex mol-ecule. A three-dimensional network is generated by N-H?N, N-H?O and C-H?O hydrogen bonds from the sulfadiazine ligands.

| S-EPMC2979398 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data