Ontology highlight
ABSTRACT:
SUBMITTER: Moore EG
PROVIDER: S-EPMC3190975 | biostudies-other | 2007 Jul
REPOSITORIES: biostudies-other
Moore Evan G EG Jocher Christoph J CJ Xu Jide J Werner Eric J EJ Raymond Kenneth N KN
Inorganic chemistry 20070613 14
The synthesis, characterization, and photophysical properties of two novel ligands, 5LINMe-1,2-HOPO (1) and H(2,2)-1,2-HOPO (2), which utilize the 1,2-HOPO chelate as a sensitizer for Eu(III) are reported. In addition, the former ligand was structurally characterized as the Eu(III) complex by X-ray crystallography. The [Eu(1)2]- complex of the tetradentate ligand (1) is stable in aqueous solution, to a limiting concentration of ca. 7x10(-9) M, and retains the superior photophysical performance n ...[more]