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Coaxial electrospun poly(methyl methacrylate)-polyacrylonitrile nanofibers: atomic force microscopy and compositional characterization.

ABSTRACT: Poly(methyl methacrylate) (PMMA)-polyacrylonitrile (PAN) fibers were prepared using a conventional single-nozzle electrospinning technique. The as-spun fibers exhibited core-shell morphology as verified by transmission electron microscopy (TEM) and atomic force microscopy (AFM). AFM-phase and modulus mapping images of the fiber cross-section and X-ray photoelectron spectroscopy (XPS) analysis indicated that PAN formed the shell and PMMA formed the core material. XPS, thermogravimetric analysis (TGA), and elemental analysis were used to determine fiber compositional information. Soaking the fibers in solvent demonstrated removal of the core material, generating hollow PAN fibers.

SUBMITTER: Zander NE

PROVIDER: S-EPMC3210579 | biostudies-other | 2011 Nov

REPOSITORIES: biostudies-other

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Coaxial electrospun poly(methyl methacrylate)-polyacrylonitrile nanofibers: atomic force microscopy and compositional characterization.

Zander Nicole E NE Strawhecker Kenneth E KE Orlicki Joshua A JA Rawlett Adam M AM Beebe Thomas P TP

The journal of physical chemistry. B 20111007 43

Poly(methyl methacrylate) (PMMA)-polyacrylonitrile (PAN) fibers were prepared using a conventional single-nozzle electrospinning technique. The as-spun fibers exhibited core-shell morphology as verified by transmission electron microscopy (TEM) and atomic force microscopy (AFM). AFM-phase and modulus mapping images of the fiber cross-section and X-ray photoelectron spectroscopy (XPS) analysis indicated that PAN formed the shell and PMMA formed the core material. XPS, thermogravimetric analysis ( ...[more]

PMID: 21928836

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