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Bis{2-[3-(hy-droxy-imino-?N)butan-2-yl-idene]-N-methyl-hydrazinecarbothio-amide-?N,S}nickel(II) dichloride.

ABSTRACT: The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H?Cl and O-H?Cl hydrogen bonds into infinite chains propagating along [10[Formula: see text]]. Weak inter-molecular C-H?O and C-H?Cl hydrogen bonds are also observed.

SUBMITTER: Abduelftah HS 

PROVIDER: S-EPMC3274853 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Bis{2-[3-(hy-droxy-imino-κN)butan-2-yl-idene]-N-methyl-hydrazinecarbothio-amide-κN,S}nickel(II) dichloride.

Abduelftah Halema Shaban HS   Qasem Ali Amna A   Eltayeb Naser Eltaher NE   Teoh Siang Guan SG   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

The asymmetric unit of the title compound, [Ni(C(6)H(12)N(4)OS)(2)]Cl(2), contains two independent Ni(II) complex cations and four chloride anions. Each Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H⋯Cl and O-H⋯Cl hydrogen bonds into infinite chains propagating along [10[Formula: see text]]. Weak inter-molecular C-H⋯O and  ...[more]

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