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Bis{N-ethyl-2-[3-(hy-droxy-imino-?N)butan-2-yl-idene]hydrazinecarbothio-amide-?N,S}nickel(II) dichloride.

ABSTRACT: In the title complex, [Ni(C(7)H(14)N(4)OS)(2)]Cl(2), the Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, mol-ecules are linked through N-H?Cl and O-H?Cl hydrogen bonds into an infinite chain propagating along [101].

SUBMITTER: Abduelftah HS

PROVIDER: S-EPMC3274909 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Bis{N-ethyl-2-[3-(hy-droxy-imino-κN)butan-2-yl-idene]hydrazinecarbothio-amide-κN,S}nickel(II) dichloride.

Abduelftah Halema Shaban HS Ali Amna Qasem AQ Eltayeb Naser Eltaher NE Teoh Siang Guan SG Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

In the title complex, [Ni(C(7)H(14)N(4)OS)(2)]Cl(2), the Ni(II) ion is six-coordinated in a distorted octa-hedral geometry by four N atoms from the two imine and two oxime groups, and two S atoms from the thione groups. Two chloride ions complete the asymmetric unit. In the crystal, mol-ecules are linked through N-H⋯Cl and O-H⋯Cl hydrogen bonds into an infinite chain propagating along [101]. ...[more]

PMID: 22346856

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