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1-[(Z)-2-Butyl-tellan-yl-1-chloro-ethen-yl]-cyclo-hex-1-ene.

ABSTRACT: The Te(II) atom in the title mol-ecule, C(12)H(19)ClTe, is coordinated in a V-shaped geometry by C atoms derived from the disparate organic substituents. A short intramolecular C-H?Cl contact occurs owing to the proximity of the ethene bond in the six-membered ring to the Cl atom. In the crystal, mol-ecules assemble into layers parallel to the ac plane, with the closest inter-actions between them being of the Te?Te type [3.9993?(16)?Å].

SUBMITTER: Zukerman-Schpector J

PROVIDER: S-EPMC3297909 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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1-[(Z)-2-Butyl-tellan-yl-1-chloro-ethen-yl]-cyclo-hex-1-ene.

Zukerman-Schpector Julio J Caracelli Ignez I Guadagnin Rafael Carlos RC Stefani Hélio A HA Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

The Te(II) atom in the title mol-ecule, C(12)H(19)ClTe, is coordinated in a V-shaped geometry by C atoms derived from the disparate organic substituents. A short intramolecular C-H⋯Cl contact occurs owing to the proximity of the ethene bond in the six-membered ring to the Cl atom. In the crystal, mol-ecules assemble into layers parallel to the ac plane, with the closest inter-actions between them being of the Te⋯Te type [3.9993 (16) Å]. ...[more]

PMID: 22412712

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