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Aqua{4,4',6,6'-tetrachloro-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc.

ABSTRACT: The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent mol-ecules. The geometry around the Zn(II) atoms is distorted trigonal-bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating water mol-ecule. The dihedral angles between the benzene rings in the two mol-ecules are 34.10?(15)?Å and 30.61?(15)?Å. In the crystal, neighbouring independent mol-ecules are linked by pairs of O-H?O hydrogen bonds, forming dimers with R(2) (2)(6) ring motifs, and by O-H?Cl hydrogen bonds. There are short Cl?Cl [3.4728?(16), 3.4863?(16), and 3.388?(1)?Å] contacts present, and mol-ecules are also linked by C-H?O and ?-? [centroid-centroid distance = 3.671?(2)?Å] inter-actions.

SUBMITTER: Kargar H

PROVIDER: S-EPMC3393198 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

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Aqua{4,4',6,6'-tetrachloro-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}zinc.

Kargar Hadi H Kia Reza R Abbasian Saeideh S Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120616 Pt 7

The asymmetric unit of the title compound, [Zn(C(19)H(16)Cl(4)N(2)O(2))(H(2)O)], comprises two crystallographically independent mol-ecules. The geometry around the Zn(II) atoms is distorted trigonal-bipyramidal, supported by the N(2)O(2) donor atoms of the tetradentate Schiff base and a coordinating water mol-ecule. The dihedral angles between the benzene rings in the two mol-ecules are 34.10 (15) Å and 30.61 (15) Å. In the crystal, neighbouring independent mol-ecules are linked by pairs of O-H⋯ ...[more]

PMID: 22807766

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