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Aquachloridobis[2-(1,3-thia-zol-4-yl-?N)-1H-benzimidazole-?N(3)]nickel(II) nitrate.

ABSTRACT: In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-H?O, N-H?O and N-H?Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. ?-? inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [centroid-centroid distances = 3.592?(3) and 3.735?(3)?Å].

SUBMITTER: Liang P

PROVIDER: S-EPMC3414103 | biostudies-other | 2012 Aug

REPOSITORIES: biostudies-other

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Aquachloridobis[2-(1,3-thia-zol-4-yl-κN)-1H-benzimidazole-κN(3)]nickel(II) nitrate.

Liang Peng P Wu Wei W Tian Wei-Man WM Yin Xian-Hong XH

Acta crystallographica. Section E, Structure reports online 20120704 Pt 8

In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-H⋯O, N-H⋯O and N-H⋯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. π-π inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [c ...[more]

PMID: 22904710

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