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Chlorido[1-(4,5-dihydro-1,3-thia-zol-2-yl-?N)ethanone thio-semicarbazonato-?N,S]nickel(II).

ABSTRACT: In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio-semicarbazone ligand via its thia-zoline N, azomethine N and thiol-ate S atoms. Short inter-molecular N-H?Cl and C-H?S contacts are present in the crystal structure.

SUBMITTER: Vinuelas-Zahinos E

PROVIDER: S-EPMC3050191 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Chlorido[1-(4,5-dihydro-1,3-thia-zol-2-yl-κN)ethanone thio-semicarbazonato-κN,S]nickel(II).

Viñuelas-Zahínos Emilio E Luna-Giles Francisco F Torres-García Pablo P Bernalte-García Alvaro A

Acta crystallographica. Section E, Structure reports online 20101215 Pt 1

In the title compound, [Ni(C(6)H(9)N(4)S(2))Cl], the Ni atom is in a slightly distorted square-planar environment coordinated by a Cl atom and a deprotonated thio-semicarbazone ligand via its thia-zoline N, azomethine N and thiol-ate S atoms. Short inter-molecular N-H⋯Cl and C-H⋯S contacts are present in the crystal structure. ...[more]

PMID: 21522596

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