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N,N-Di-phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro-lin-2-yl)-aniline ethanol monosolvate.

ABSTRACT: The title compound, C32H21N4·C2H5OH, crystallized as an ethanol monosolvate. In the mol-ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54?(13)°. The tri-phenyl-amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92?(16) and 70.81?(15)°. In the crystal, the phenanthroline mol-ecules are linked via the solvent mol-ecule by N-H?O, O-H?N and C-H?O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C-H?N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions.

SUBMITTER: Luo JS

PROVIDER: S-EPMC3647870 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

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N,N-Di-phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro-lin-2-yl)-aniline ethanol monosolvate.

Luo Jun-Shan JS Zhang Yan-Yan YY Liu Zhao-Di ZD Tian Yu-Peng YP

Acta crystallographica. Section E, Structure reports online 20130410 Pt 5

The title compound, C32H21N4·C2H5OH, crystallized as an ethanol monosolvate. In the mol-ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri-phenyl-amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol-ecules are linked via the solvent mol-ecule by N-H⋯O, O-H⋯N and C ...[more]

PMID: 23723836

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