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(Thio-cyanato-?S)-tris-(thio-urea-?S)mercury(II) chloride.

ABSTRACT: In the title salt, [Hg(NCS)(CH4N2S)3]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra-hedral manner by three thio-urea groups and one thio-cyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39?(5) to 128.02?(4)°. Weak intra-molecular N-H?S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N-H?N and weak N-H?Cl inter-actions, generating a three-dimensional network.

SUBMITTER: Shihabuddeen Syed A

PROVIDER: S-EPMC3684862 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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(Thio-cyanato-κS)-tris-(thio-urea-κS)mercury(II) chloride.

Shihabuddeen Syed A A Rajarajan K K Nizammohideen M M

Acta crystallographica. Section E, Structure reports online 20130504 Pt 6

In the title salt, [Hg(NCS)(CH4N2S)3]Cl, the Hg(2+) ion is coordinated in a severely distorted tetra-hedral manner by three thio-urea groups and one thio-cyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intra-molecular N-H⋯S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N-H⋯N and weak N-H⋯Cl inter-actions, generating a three-dimensional network. ...[more]

PMID: 23794964

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